Enhancement in Li+/Mg(2+)separation from salt lake brine with PDA-PEI composite nanofiltration membrane
文献类型:期刊论文
作者 | Ashraf, Muhammad Awais3,4; Wang, Junfeng2,4; Wu, Baichun1; Cui, Penglei4; Xu, Baohua4; Li, Xingchun1 |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2020-07-04 |
页码 | 11 |
关键词 | coatings membranes separation techniques |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.49549 |
英文摘要 | Extraction of lithium from high Mg2+/Li(+)ratio salt lake brine with the nanofiltration (NF) membrane is significantly challenging. Interfacial polymerization was utilized for the facile modification of NF membranes with polydopamine (PDA) and polyethylenimine (PEI) to enhance lithium separation efficiency. Comparing permeability and salts rejection (Li(+)and Mg2+) of three NF membranes before and after PDA/PEI deposition, it was observed that separation efficiency was not only dependent on steric hindrance but also affected by Donnan exclusion mechanism. In the case of NF270 membrane after facile polymerization, due to small pore size distribution and low charge density confirmed by zeta potential measurements, Li(+)permeability was reached about 95% at a flux of 21.33 L center dot m(-2)center dot h(-1). Although with the DK membrane, separation factor SF(Li/Mg)was also increased up to 60 after modification, the pore narrowing effect significantly decreased lithium permeability and flux. Experimental results showed that facile modification not only enhanced stability and hydrophilicity but also reduced the high Mg2+/Li(+)ratio from 30 to 4.1 in single-stage separation. |
WOS关键词 | LITHIUM AVAILABILITY ; SURFACE MODIFICATION ; HIGH REJECTION ; SEPARATION ; POLYDOPAMINE ; PERFORMANCE ; RESOURCES ; MAGNESIUM ; REMOVAL ; MICRO |
资助项目 | CAS-TWAS President's Fellowship Program ; Fujian Innovation Academy, Chinese Academy of Sciences[FJCXY18040101] ; Innovative Research Group Project of the National Natural Science Foundation of China (CN)[21890762] ; Key Research Program of Frontier Sciences CAS[QYZDY-SSW-JSC011] ; National Natural Science Foundation of China[21978302] ; National Natural Science Foundation of China[21776292] |
WOS研究方向 | Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000545083700001 |
出版者 | WILEY |
资助机构 | CAS-TWAS President's Fellowship Program ; Fujian Innovation Academy, Chinese Academy of Sciences ; Innovative Research Group Project of the National Natural Science Foundation of China (CN) ; Key Research Program of Frontier Sciences CAS ; National Natural Science Foundation of China |
源URL | [http://ir.ipe.ac.cn/handle/122111/41383] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Wang, Junfeng; Li, Xingchun |
作者单位 | 1.CNPC Res Inst Safety & Environm Technol, State Key Lab Petr Pollut Control, Beijing 102206, Peoples R China 2.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing, Peoples R China 3.Univ Chinese Acad Sci, Chem Engn, Beijing, Peoples R China 4.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Ashraf, Muhammad Awais,Wang, Junfeng,Wu, Baichun,et al. Enhancement in Li+/Mg(2+)separation from salt lake brine with PDA-PEI composite nanofiltration membrane[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2020:11. |
APA | Ashraf, Muhammad Awais,Wang, Junfeng,Wu, Baichun,Cui, Penglei,Xu, Baohua,&Li, Xingchun.(2020).Enhancement in Li+/Mg(2+)separation from salt lake brine with PDA-PEI composite nanofiltration membrane.JOURNAL OF APPLIED POLYMER SCIENCE,11. |
MLA | Ashraf, Muhammad Awais,et al."Enhancement in Li+/Mg(2+)separation from salt lake brine with PDA-PEI composite nanofiltration membrane".JOURNAL OF APPLIED POLYMER SCIENCE (2020):11. |
入库方式: OAI收割
来源:过程工程研究所
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