Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate
文献类型：期刊论文
| 作者 | Yang, Zifeng1,2; Liu, Lei2; An, Hongzhe2; Li, Chenhao2; Zhang, Zhencai2; Fang, Wenjuan2; Xu, Fei2; Zhang, Suojiang1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2020-07-13 |
| 卷号 | 8期号:27页码:9968-9979 |
| 关键词 | Renewable Isosorbide Dimethyl carbonate Biobased polycarbonate Cost-effective |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.0c00430 |
| 英文摘要 | Green synthesis of poly(isosorbide carbonate) (PIC) with remarkable properties is a huge challenge in industrial applications due to low molecular weight and harsh reaction conditions. We reported a novel pathway to synthesize high molecular weight PIC through melt polymerization of isosorbide (ISB) and dimethyl carbonate (DMC), which are derived from the biomass and CO2, respectively. The effects of metal ion-containing compound catalyst on chemical structures, terminal groups, and molecular weight of PIC in the process of melt polycondensation were studied. Compared with the best reported catalyst lithium acetylacetonate, the weight-average molecular weight (M-w) of PIC was increased by using our preferred catalyst sodium tert-butoxide from 46 500 to 55 100 with the ISB conversion up to 99.0%, and the reaction time was decreased from 12 h to only 2.5 h, as far as we know, which is the highest M-w value and the most efficient catalyst achieved by one-step method. According to the results of the experiment and simulation, we found that high catalytic performance was ascribed to the weak interaction energy of anion-cation of catalyst and the strong proton acceptance ability of the anion of the catalyst. Meanwhile, increasing the interaction energy of anion-cation of the catalyst could inhibit the occurrence of the methylation side reaction and interestingly the activated endohydroxyl groups of ISB were found to be more easily methylated. Finally, based on the captured and detected intermediates of the two-stages of the reaction, a possible mechanim for the synergetic effects of cation-anion through hydrogen bond formation was proposed. |
| WOS关键词 | CATALYST ; TRANSFORMATION ; EFFICIENT ; POLYMERS |
| 资助项目 | National Natural Science Foundation of China[21878316] ; Strategic Fundation of Chinese Academy of Sciences[Y941081135] ; Chinese Academy of Sciences[XDA21031000] ; National Key R&D Program of China[2016YFB0600903] ; International Partnership Program of Chinese Academy of Sciences[122111KYSB20190029] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000551360900004 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Strategic Fundation of Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Key R&D Program of China ; International Partnership Program of Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/41508]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xu, Fei; Zhang, Suojiang |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Zifeng,Liu, Lei,An, Hongzhe,et al. Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(27):9968-9979. |
| APA | Yang, Zifeng.,Liu, Lei.,An, Hongzhe.,Li, Chenhao.,Zhang, Zhencai.,...&Zhang, Suojiang.(2020).Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(27),9968-9979. |
| MLA | Yang, Zifeng,et al."Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.27(2020):9968-9979. |
入库方式： OAI收割
来源：过程工程研究所
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