Biodegradable functional chitosan membrane for enhancement of artemisinin purification
文献类型：期刊论文
| 作者 | Cao, Yingying2,3; Zhang, Yongqiang2,3; Zhang, Ying3; Wang, Ling3; Lv, Lunchao1; Ma, Xifei2,3; Zeng, Shaojuan3; Wang, Hui2,3 |
| 刊名 | CARBOHYDRATE POLYMERS
 |
| 出版日期 | 2020-10-15 |
| 卷号 | 246页码:11 |
| 关键词 | Functional chitosan membrane Artemisinin Purification Mechanism Kinetics |
| ISSN号 | 0144-8617 |
| DOI | 10.1016/j.carbpol.2020.116590 |
| 英文摘要 | Artemisinin is mainly derived from Artemisia annua L. Since the leaves composition is complex, artemisinin purification faces great challenges. In this work, functional chitosan membranes were fabricated by a one-step hydrolysis method through grafting long-chain alkyl group on the surface of chitosan to increase its hydro-phobicity. The as-prepared membranes were used to adsorb wax oil (i.e., the impurity components) in Artemisia annua L. and to avoid co-precipitation of wax oil along with artemisinin using the crystallization technique for purification. Octyl-trimethoxysilane modified chitosan membrane (FCM-C8) showed excellent capability to in-tensify this purification process. The product purity could reach more than 98 % using one crystallization step under the optimal conditions, and in this case, adsorption capacity of FCM-C8 for wax oil was 478.9 mg/g. In addition, the adsorption kinetics and mechanism of wax oil on FCM-C8 were studied. The membrane can si-multaneously adsorb multiple components in wax oil through interactions like electrostatic forces, hydrogen bondings. |
| WOS关键词 | DYE REMOVAL ; ACID DYES ; ADSORPTION ; FABRICATION ; EXTRACTION ; QUANTIFICATION ; EQUILIBRIUM ; FLAVONOIDS ; ADSORBENT ; CANCER |
| 资助项目 | National Key R&D Program of China[2017YFB0603401-03] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A12] ; CAS Pioneer Hundred Talents Program ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Chemistry ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000554907700014 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R&D Program of China ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; CAS Pioneer Hundred Talents Program ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/41577]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Hui |
| 作者单位 | 1.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc,Inst Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Yingying,Zhang, Yongqiang,Zhang, Ying,et al. Biodegradable functional chitosan membrane for enhancement of artemisinin purification[J]. CARBOHYDRATE POLYMERS,2020,246:11. |
| APA | Cao, Yingying.,Zhang, Yongqiang.,Zhang, Ying.,Wang, Ling.,Lv, Lunchao.,...&Wang, Hui.(2020).Biodegradable functional chitosan membrane for enhancement of artemisinin purification.CARBOHYDRATE POLYMERS,246,11. |
| MLA | Cao, Yingying,et al."Biodegradable functional chitosan membrane for enhancement of artemisinin purification".CARBOHYDRATE POLYMERS 246(2020):11. |
入库方式： OAI收割
来源：过程工程研究所
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