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Core-shell gold-nickel nanostructures as highly selective and stable nonenzymatic glucose sensor for fermentation process

文献类型：期刊论文

作者Gao, Xuejin5; Du, Xinzhao5; Liu, Danye4; Gao, Huihui1,2,3,5; Wang, Pu1,2,3,5; Yang, Jun4
刊名SCIENTIFIC REPORTS
出版日期2020-01-28
卷号10期号:1页码:10
ISSN号2045-2322
DOI10.1038/s41598-020-58403-x
英文摘要Non-enzymatic electrodes based on noble metals have excellent selectivity and high sensitivity in glucose detection but no such shortcomings as easy to be affected by pH, temperature, and toxic chemicals. Herein, spherical gold-nickel nanoparticles with a core-shell construction (Au@Ni) are prepared by oleylamine reduction of their metal precursors. At an appropriate Au/Ni ratio, the core-shell Au@Ni nanoparticles as a sensor for glucose detection combine the high electrocatalytic activity, good selectivity and biological compatibility of Au with the remarkable tolerance of Ni for chlorine ions (Cl-) and poisoning intermediates in catalytic oxidation of glucose. This electrode exhibits a low operating voltage of 0.10 V vs. SCE for glucose oxidation, leading to higher selectivity compared with other Auand Ni-based sensors. The linear range for the glucose detection is from 0.5 mmol L-1 to 10 mmol L-1 with a rapid response time of ca. 3 s, good stability, sensitivity estimated to be 23.17 mu A cm(-2) mM(-1), and a detection limit of 0.0157 mM. The sensor displays high anti-toxicity, and is not easily poisoned by the adsorption of Cl- in solution.
WOS关键词REDUCED GRAPHENE OXIDE ; ELECTROCHEMICAL OXIDATION ; NANOPARTICLES ; CARBON ; PERFORMANCE ; BIOSENSOR ; ARRAYS ; NANOCOMPOSITE ; DEPOSITION ; ELECTRODE
资助项目National Natural Science Foundation of China[61640312] ; National Natural Science Foundation of China[61763037] ; National Natural Science Foundation of China[21573240] ; National Natural Science Foundation for Young Scientists of China[61803005] ; Natural Science Foundation of Beijing Municipality[4172007] ; Natural Science Foundation of Beijing Municipality[4192011] ; Beijing Municipal Commission of Education
WOS研究方向Science & Technology - Other Topics
语种英语
WOS记录号WOS:000562864700006
出版者NATURE PUBLISHING GROUP
资助机构National Natural Science Foundation of China ; National Natural Science Foundation for Young Scientists of China ; Natural Science Foundation of Beijing Municipality ; Beijing Municipal Commission of Education
源URL[http://ir.ipe.ac.cn/handle/122111/41813]  
专题中国科学院过程工程研究所
通讯作者Yang, Jun
作者单位1.Beijing Univ Technol, Beijing Key Lab Computat Intelligence & Intellige, Beijing 100124, Peoples R China
2.Beijing Univ Technol, Beijing Lab Urban Mass Transit, Beijing 100124, Peoples R China
3.Beijing Univ Technol, Engn Res Ctr Digital Community, Minist Educ, Beijing 100124, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
5.Beijing Univ Technol, Fac Informat Technol, Beijing 100124, Peoples R China
推荐引用方式
GB/T 7714		 Gao, Xuejin,Du, Xinzhao,Liu, Danye,et al. Core-shell gold-nickel nanostructures as highly selective and stable nonenzymatic glucose sensor for fermentation process[J]. SCIENTIFIC REPORTS,2020,10(1):10.
APA Gao, Xuejin,Du, Xinzhao,Liu, Danye,Gao, Huihui,Wang, Pu,&Yang, Jun.(2020).Core-shell gold-nickel nanostructures as highly selective and stable nonenzymatic glucose sensor for fermentation process.SCIENTIFIC REPORTS,10(1),10.
MLA Gao, Xuejin,et al."Core-shell gold-nickel nanostructures as highly selective and stable nonenzymatic glucose sensor for fermentation process".SCIENTIFIC REPORTS 10.1(2020):10.

入库方式： OAI收割

来源：过程工程研究所

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