Novel Pd/MOF electrocatalyst for hydrogen evolution reaction
文献类型：期刊论文
| 作者 | Nie, Ming1; Sun, Hai1; Lei, Dan1; Kang, Shuai2 ; Liao, Jianming1; Guo, Peitao1; Xue, Zhenhong1; Xue, Fengjuan1
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| 刊名 | MATERIALS CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2020-11-01 |
| 卷号 | 254页码:7 |
| 关键词 | Metal-organic framework HER Electrocatalyst |
| ISSN号 | 0254-0584 |
| DOI | 10.1016/j.matchemphys.2020.123481 |
| 通讯作者 | Nie, Ming(niemingcqu@126.com) |
| 英文摘要 | Weak electrical conduction impedes the application of Metal-organic framework (MOF) in electrochemistry. In this work, palladium-based MOF (Pd/MOF) is synthesized via i) simple solvothermal process and ii) direct chemical reduction method. N-2 adsorption-desorption isotherms and thermogravimetric analyzer show that MOF have large specific surface area and good thermal stability. The synthesized materials were tested in acidic condition for hydrogen evolution reaction (HER). Electrochemical test results show that Pd/MOF with tafel slope of 85 mV.dec(-1), onset overpotential of 105 mV and ideal stability has better performance than bulk MOF for HER. The enhanced performance can be ascribed to the large porosity and specific surface of MOF, and the synergistic effect between Pd and MOF toward H-2 production. |
| 资助项目 | Chongqing Key Laboratory for Advanced Materials & Technologies of Clean Energies[JJNY202002] ; Fundamental Research Funds for the Central Universities[XDJK2020B004] ; Chongqing Graduate Student Research Innovation Project[CYS19106] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000569784400010 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/11820]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Nie, Ming |
| 作者单位 | 1.Southwest Univ, Sch Mat & Energy, Chongqing Key Lab Adv Mat & Technol Clean Energie, Chongqing 400715, Peoples R China 2.Chinese Acad Sci, Micronano Mfg & Syst Integrat Ctr, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nie, Ming,Sun, Hai,Lei, Dan,et al. Novel Pd/MOF electrocatalyst for hydrogen evolution reaction[J]. MATERIALS CHEMISTRY AND PHYSICS,2020,254:7. |
| APA | Nie, Ming.,Sun, Hai.,Lei, Dan.,Kang, Shuai.,Liao, Jianming.,...&Xue, Fengjuan.(2020).Novel Pd/MOF electrocatalyst for hydrogen evolution reaction.MATERIALS CHEMISTRY AND PHYSICS,254,7. |
| MLA | Nie, Ming,et al."Novel Pd/MOF electrocatalyst for hydrogen evolution reaction".MATERIALS CHEMISTRY AND PHYSICS 254(2020):7. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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