Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity
文献类型：期刊论文
| 作者 | Jiang H(姜恒) ; Feng YF(冯亚菲); Chen M(陈猛); Wang YR(王育人)
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| 刊名 | International Journal of Hydrogen Energy
 |
| 出版日期 | 2013-08-21 |
| 卷号 | 38期号:25页码:10950-10955 |
| 通讯作者邮箱 | yurenwang@imech.ac.cn |
| 关键词 | Metal-organic frameworks Interpenetrated structure Hydrogen-storage Multi-walled carbon nanotubes High mesoporosity |
| ISSN号 | 0360-3199 |
| 产权排序 | [Jiang, Heng; Feng, Yafei; Chen, Meng; Wang, Yuren] Key Laboratory of Microgravity, Institute of Mechanics, Chinese Academy of Sciences, No.15 Beisihuanxi Road, Beijing 100190, PR China |
| 通讯作者 | Wang, YR (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv Sci, Beijing 100190, Peoples R China. |
| 中文摘要 | Metal-organic frameworks (MOFs) exhibiting high surface area and tunable pore size own broad application prospects. Compared with existing MOFs, MOF-5 [Zn4O(bdc)3] is a promising hydrogen storage material due to high H2 uptake capacity and thermostability. However, further wider applications of MOF-5 have been limited because atmospheric moisture levels cause MOF-5 instability. MOF-5 and multi-walled carbon nanotubes (MWCNTs) hybrid composite (denoted MOFMC) can enhance stability toward ambient moisture and improve hydrogen storage capacity. In this paper, the MOFMC, which has an interpenetrated structure with high mesoporosity, was synthesized. The MOFMC is denoted as Int-MOFMC-meso. It stored 2.02 wt% H2 at 77 K under 1 bar, which is higher than the MOF-5 with similar structure and the earlier reported MOFMC material. Moreover, the Int-MOFMC-meso can also show more excellent performance of thermostability and moisture stability than the MOF-5 with similar structure. |
| 学科主题 | 新型材料的力学问题 |
| 类目[WOS] | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; NANOPOROUS MATERIALS ; SORPTION PROPERTIES ; ADSORPTION ; CARBON ; MOF-5 ; INCLUSION ; BEHAVIORS ; DESIGN ; SIZE |
| 收录类别 | SCI ; EI |
| 资助信息 | The authors wish to acknowledge the support from the National Natural Science Foundation of China (Nos. 11202211 and 11272315). |
| 原文出处 | http://dx.doi.org/10.1016/j.ijhydene.2013.03.044 |
| 语种 | 英语 |
| WOS记录号 | WOS:000324563100096 |
| 公开日期 | 2013-09-12 |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/47434]  |
| 专题 | 力学研究所_国家微重力实验室 |
| 推荐引用方式 GB/T 7714 | Jiang H,Feng YF,Chen M,et al. Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity[J]. International Journal of Hydrogen Energy,2013,38(25):10950-10955. |
| APA | 姜恒,冯亚菲,陈猛,&王育人.(2013).Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity.International Journal of Hydrogen Energy,38(25),10950-10955. |
| MLA | 姜恒,et al."Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity".International Journal of Hydrogen Energy 38.25(2013):10950-10955. |
入库方式： OAI收割
来源：力学研究所
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