Atomically dispersed Fe-N-S-C anchored on pomegranate-shaped carbon spheres for oxygen reduction reaction and all-solid-state zinc-air battery
文献类型：期刊论文
| 作者 | Jiang, P.1,2,5; Chen, S.1,2 ; Wang, C.1,2,6; Wang, D.7; Diao, J.1,2; Cao, Z.4; Lin, Z.1,2; Luo, Q.1,2; Lu, J.1,2; Huang, H.1,2
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| 刊名 | MATERIALS TODAY SUSTAINABILITY
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| 出版日期 | 2020-09-01 |
| 卷号 | 9 |
| 关键词 | Oxygen reduction reaction Flexible Zn-air battery Single atom Fe-N-S-C nitrogen-sulfur dual-doped porous carbon FeNx |
| ISSN号 | 2589-2347 |
| DOI | 10.1016/j.mtsust.2020.100039 |
| 通讯作者 | Hu, L.(hulin@hmfl.ac.cn) ; Chen, Q.(cqw@ustc.edu.cn) |
| 英文摘要 | Flexible Zn-air battery (ZAB) plays a pivotal role in the eventual realization of wearable/portable electronic devices such as hearing aids and electronic wristwatches owing to its high energy density and stable working voltage. However, the efficiency and long-term durability are still inevitably limited by the sluggish kinetics of oxygen reduction reaction (ORR) in air electrode. Herein, we fabricated a planar all-solid-state rechargeable ZAB with excellent scalability by integrating atomically dispersed FeNx anchored on nitrogen-sulfur dual-doped porous carbon spheres and a highly conductive poly (acryl-amide-co-acrylic acid) solid polymer alkaline electrolyte. Owing to the introduction of sulfur in carbon substrate, the catalyst exhibits superior ORR performance over 20% commercial Pt/C. Specially, it also displays outstanding all-solid-state ZAB capacity with a maximum power density of 85.5 mW/cm(2), as well as ultralong cycle life for more than 40 h, which outperforms that of most conventional polyvinyl alcohol alkaline gel electrolyte-based flexible quasi-solid-state or all-solid-state ZAB. Density functional theory results reveal that the dopants N and S play a synergetic interplay in modulating the electronic structure of atomically dispersed FeNx species and provide a fast electron transfer path for ORR. (C) 2020 Elsevier Ltd. All rights reserved. |
| WOS关键词 | ACTIVE-SITES ; ELECTROCATALYSTS ; COORDINATION ; EVOLUTION ; SULFUR |
| 资助项目 | National Natural Science Foundation (NSFC)[51772283] ; National Natural Science Foundation (NSFC)[21271163] ; National Natural Science Foundation (NSFC)[21972145] ; National Key R&D Program of China[2016YFA0401801] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000612951300007 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation (NSFC) ; National Key R&D Program of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/119668]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Hu, L.; Chen, Q. |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Mat Sci & Engn, Hefei 230026, Peoples R China 2.Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Hefei Inst Phys Sci, Anhui Key Lab Condensed Mater Phys Extreme Condit, High Magnet Field Lab, Hefei 230031, Peoples R China 4.Anhui Univ, Sch Phys & Mat Sci, Inst Phys Sci & Informat Technol, Hefei 230601, Peoples R China 5.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 6.City Univ Hong Kong, Ctr Super Diamond & Adv Films COSDAF, Dept Mat Sci & Engn, Kowloon, Tat Chee Ave, Hong Kong, Peoples R China 7.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, 21 Nanyang Link, Singapore 637371, Singapore |
| 推荐引用方式 GB/T 7714 | Jiang, P.,Chen, S.,Wang, C.,et al. Atomically dispersed Fe-N-S-C anchored on pomegranate-shaped carbon spheres for oxygen reduction reaction and all-solid-state zinc-air battery[J]. MATERIALS TODAY SUSTAINABILITY,2020,9. |
| APA | Jiang, P..,Chen, S..,Wang, C..,Wang, D..,Diao, J..,...&Chen, Q..(2020).Atomically dispersed Fe-N-S-C anchored on pomegranate-shaped carbon spheres for oxygen reduction reaction and all-solid-state zinc-air battery.MATERIALS TODAY SUSTAINABILITY,9. |
| MLA | Jiang, P.,et al."Atomically dispersed Fe-N-S-C anchored on pomegranate-shaped carbon spheres for oxygen reduction reaction and all-solid-state zinc-air battery".MATERIALS TODAY SUSTAINABILITY 9(2020). |
入库方式： OAI收割
来源：合肥物质科学研究院
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