Transformation details of poly(acrylonitrile) to poly(amidoxime) during the amidoximation process
文献类型：期刊论文
| 作者 | Shao, Dadong1; Hou, Guangshun2; Chi, Fangting3; Lu, Xirui3; Ren, Xuemei4
|
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2021-01-22 |
| 卷号 | 11 |
| DOI | 10.1039/d0ra09096d |
| 通讯作者 | Shao, Dadong(shaodadong@126.com) ; Hou, Guangshun(houguangshun@163.com) |
| 英文摘要 | During the amidoximation process, transformation details of poly(acrylonitrile) (PAN) to poly(amidoxime) (PAO) is critical for optimizing amidoximation conditions, which determine the physicochemical properties and adsorption capabilities of PAO-based materials. Although the optimization of amidoximation conditions can be reported in the literature, a detailed research on the transformation is still missing. Herein, the effect of the amidoximation conditions (i.e. temperature, time, and NH2OH concentration) on the physicochemical properties and adsorption capabilities of PAO was studied in detail. The results showed that the extent of amidoximation reaction increased with increasing temperature, time, and NH2OH concentration. However, a considerably high temperature (>60 degrees C) and a considerably long time (>3 h) could result in the degradation and decomposition of PAO's surface topologies and functional groups, and then decrease its adsorption capability for U(vi). The optimal amidoximation condition was 3 h, 60 degrees C and 50 g L-1 NH2OH. At this condition, the PAO obtained presented the highest adsorption capability for U(vi) under experimental conditions. These results provide pivotal information on the transformation of PAO-based materials during the amidoximation process. |
| WOS关键词 | TRANSFER RADICAL POLYMERIZATION ; URANIUM ADSORBENT FIBERS ; ADSORPTION ; SEAWATER ; RECOVERY ; EXTRACTION ; POLYPROPYLENE ; COMPLEXATION ; SORBENTS ; ELUTION |
| 资助项目 | National Natural Science Foundation of China[11675210] ; National Natural Science Foundation of China[21976089] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000609773700001 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/119748]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Shao, Dadong; Hou, Guangshun |
| 作者单位 | 1.Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Peoples R China 2.Henan Polytech Univ, Inst Resources & Environm, Jiaozuo 454000, Henan, Peoples R China 3.Southwest Univ Sci & Technol, Fundamental Sci Nucl Wastes & Environm Safety Lab, Mianyang 621010, Sichuan, Peoples R China 4.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Dadong,Hou, Guangshun,Chi, Fangting,et al. Transformation details of poly(acrylonitrile) to poly(amidoxime) during the amidoximation process[J]. RSC ADVANCES,2021,11. |
| APA | Shao, Dadong,Hou, Guangshun,Chi, Fangting,Lu, Xirui,&Ren, Xuemei.(2021).Transformation details of poly(acrylonitrile) to poly(amidoxime) during the amidoximation process.RSC ADVANCES,11. |
| MLA | Shao, Dadong,et al."Transformation details of poly(acrylonitrile) to poly(amidoxime) during the amidoximation process".RSC ADVANCES 11(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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