Zirconium doping in calcium titanate perovskite oxides with surface nanostep structure for promoting photocatalytic hydrogen evolution
文献类型：期刊论文
| 作者 | Gao, Qiang1; Meng, Jie2; Yang, Ya3,4; Lin, Qingyun1; Lu, Yangfan1; Wei, Xiao1; Li, Jixue1; Han, Gaorong1; Zhang, Ze1 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2021-03-15 |
| 卷号 | 542 |
| ISSN号 | 0169-4332 |
| 关键词 | Zr doping Surface structure CaTiO3 Electronic structures Photocatalysis |
| DOI | 10.1016/j.apsusc.2020.148544 |
| 通讯作者 | Wei, Xiao(mseweixiao@zju.edu.cn) ; Zhang, Ze(zezhang@zju.edu.cn) |
| 英文摘要 | Metal doping has been demonstrated to be an effective strategy to modulate photocatalytic properties. However, it is very challenging to achieve tunable electronic structures and controllable morphologies with more active sites only via metal doping. Herein, Zr doped CaTiO3 photocatalysts with enhanced photocatalytic activities toward the hydrogen evolution was prepared by one-step mild hydrothermal reaction. We revealed that zirconium doping would regulate the surface structures of CaTiO3 from smooth surface to characteristic nanosteps structures. This nanosteps structure with more exposed active sites accompanied by higher exposed surface area, oxygen vacancies and reduction ability, effectively promote the separation of photo-induced carriers, thus resulting in increased photocatalytic properties. This work provides a guideline for surface structures and electronic structures modification simultaneously to design powerful photocatalysts only by metal doping. |
| WOS关键词 | OXYGEN VACANCIES ; CATIO3 ; WATER ; NANOCOMPOSITE ; NANOPARTICLES ; CATALYSIS ; H-2 |
| 资助项目 | National Natural Science Foundation of China[11234011] ; National Natural Science Foundation of China[11327901] ; National Natural Science Foundation of China[51102208] ; China Scholarship Council |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000608527300005 |
| 资助机构 | National Natural Science Foundation of China ; China Scholarship Council |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/119826]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Wei, Xiao; Zhang, Ze |
| 作者单位 | 1.Zhejiang Univ, Ctr Electron Microscopy, State Key Lab Silicon Mat, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China 2.Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark 3.Chinese Acad Sci, Environm Mat & Pollut Control Lab, Inst Solid State Phys, HFIPS, Hefei 230031, Peoples R China 4.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Qiang,Meng, Jie,Yang, Ya,et al. Zirconium doping in calcium titanate perovskite oxides with surface nanostep structure for promoting photocatalytic hydrogen evolution[J]. APPLIED SURFACE SCIENCE,2021,542. |
| APA | Gao, Qiang.,Meng, Jie.,Yang, Ya.,Lin, Qingyun.,Lu, Yangfan.,...&Zhang, Ze.(2021).Zirconium doping in calcium titanate perovskite oxides with surface nanostep structure for promoting photocatalytic hydrogen evolution.APPLIED SURFACE SCIENCE,542. |
| MLA | Gao, Qiang,et al."Zirconium doping in calcium titanate perovskite oxides with surface nanostep structure for promoting photocatalytic hydrogen evolution".APPLIED SURFACE SCIENCE 542(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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