中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Photoionization studiesOf C2Cl4 using synchrotron radiation

文献类型:期刊论文

刊名ACTA PHYSICA SINICA
出版日期2006
卷号55
关键词MASS-SPECTROMETRY MOLECULES SPECTRA vacuum ultraviolet photoionization appearance potential of ions ionization potential tetrachloroethylence
ISSN号1000-3290
其他题名Photoionization studies of C2Cl4 using synchrotron radiation
英文摘要The photoionization and photodissociation processes of C2Cl4 were investigated under the supersonic molecular beam conditions by using a reflectron-time-of-flight mass spectrometer (TOF-MS) and vacuum ultraviolet (VUV) photons from synchrotron radiation source. The photoionization mass spectrum and the photoionization efficiency (PIE) curves of the parent ion and some fragment ions were measured. The appearance potentials of these ions are obtained from their PIE curves. The formation enthalpies of some major ions and the dissociation energy of C2Cl4 have been evaluated from these data. According to the experimental results and the energy calculated by G1 theory, the main possible channels of dissociative photoionization of C2Cl4 have been discussed. In the future, we can detect C2Cl4 with single photon ionization (SPI)-TOFMS technique using 118.0nm laser radiation. This is based on the mass spectrum obtained at the wavelength by using synchrotron radiation source.
语种英语
CSCD记录号CSCD:2241404
WOS记录号WOS:000234257400025
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/62109]  
专题中国科学院合肥物质科学研究院
推荐引用方式
GB/T 7714
. Photoionization studiesOf C2Cl4 using synchrotron radiation[J]. ACTA PHYSICA SINICA,2006,55.
APA (2006).Photoionization studiesOf C2Cl4 using synchrotron radiation.ACTA PHYSICA SINICA,55.
MLA "Photoionization studiesOf C2Cl4 using synchrotron radiation".ACTA PHYSICA SINICA 55(2006).

入库方式: OAI收割

来源:合肥物质科学研究院

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