Flexible Composite Solid Electrolyte with an Active Inorganic Filler
文献类型:期刊论文
作者 | Sun, Yiyang2; Wang, Jialu3; Fu, Daosong2; Zhang, Fengrui2; Wang, Zhicheng2; Chen, Xi4; Xu, Jingjing2; Hu, Jianchen1; Wu, Xiaodong2 |
刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING |
出版日期 | 2021-02-08 |
卷号 | 9 |
ISSN号 | 2168-0485 |
关键词 | composite polymer electrolyte solid electrolyte interphase all-solid-state battery molybdenum disulfide lithium dendrite |
DOI | 10.1021/acssuschemeng.0c08008 |
通讯作者 | Xu, Jingjing(jjxu2011@sinano.ac.cn) ; Hu, Jianchen(hujianchen@suda.edu.cn) ; Wu, Xiaodong(xdwu2011@sinano.ac.cn) |
英文摘要 | Solid polymer electrolytes (SPEs) attract great attention due to their wide electrochemical stability window, low cost, and excellent processability. However, some obstacles, including their low ionic conductivity, poor solid-solid contact between the SPE and lithium metal electrode, and uneven lithium deposition behavior, hinder their application in solid-state lithium batteries. Herein, a flexible composite solid electrolyte is facilely designed and successfully fabricated by introducing reactive petal-like MoS2 nanosheets to a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/lithium bis(fluorosulfonyl)imide (LiFSI) polymer electrolyte. The addition of petal-like MoS2 nanosheets not only greatly improves the room-temperature ionic conductivity to 2.8 x 10 (-4) S cm(-1) but also decreases interfacial impedance and in situ suppresses lithium dendrite growth. In the resulting solid-state batteries, both rate capacity (137 mAh g(-1) at 0.54C) and cycling stability (Coulombic efficiency in each cycle close to 100% during 200 cycles) are obtained by employing the electrolyte. In addition, the rational mechanism of MoS2 in improving ion conduction and suppressing lithium dendrite growth is suggested. |
资助项目 | Ministry of Science and Technology of China[2016YFB0100102] ; National Natural Science Foundation of China[51603135] ; National Natural Science Foundation of China[21503265] ; National Natural Science Foundation of China[22075314] ; Nano-X (Vacuum Interconnected Nanotech Workstation, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, China) |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000618670600024 |
资助机构 | Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Nano-X (Vacuum Interconnected Nanotech Workstation, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, China) |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/120176] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Xu, Jingjing; Hu, Jianchen; Wu, Xiaodong |
作者单位 | 1.Soochow Univ, Coll Text & Clothing Engn, Suzhou 215123, Jiangsu, Peoples R China 2.Chinese Acad Sci, Suzhou Inst Nanotech & NanoBion SINANO, iLab, Suzhou 215123, Peoples R China 3.Chinese Acad Sci, Ctr Environm & Energy Nanomat, Inst Solid State Phys, Hefei 230031, Peoples R China 4.Xian Jiaotong Liverpool Univ, Sch Sci, Dept Phys, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Yiyang,Wang, Jialu,Fu, Daosong,et al. Flexible Composite Solid Electrolyte with an Active Inorganic Filler[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9. |
APA | Sun, Yiyang.,Wang, Jialu.,Fu, Daosong.,Zhang, Fengrui.,Wang, Zhicheng.,...&Wu, Xiaodong.(2021).Flexible Composite Solid Electrolyte with an Active Inorganic Filler.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9. |
MLA | Sun, Yiyang,et al."Flexible Composite Solid Electrolyte with an Active Inorganic Filler".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9(2021). |
入库方式: OAI收割
来源:合肥物质科学研究院
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