Flexible Carbon Nanotubes Confined Yolk-Shelled Silicon-Based Anode with Superior Conductivity for Lithium Storage
文献类型：期刊论文
| 作者 | Han, Na2; Li, Jianjiang2; Wang, Xuechen2; Zhang, Chuanlong2; Liu, Gang2; Li, Xiaohua2; Qu, Jing2; Peng, Zhi2; Zhu, Xiaoyi2; Zhang, Lei1,3
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| 刊名 | NANOMATERIALS
 |
| 出版日期 | 2021-03-01 |
| 卷号 | 11 |
| 关键词 | silicon yolk− shell structure anode lithium-ion batteries |
| DOI | 10.3390/nano11030699 |
| 通讯作者 | Zhu, Xiaoyi(xyzhu@qdu.edu.cn) ; Zhang, Lei(lei.zhang@issp.ac.cn) |
| 英文摘要 | The further deployment of silicon-based anode materials is hindered by their poor rate and cycling abilities due to the inferior electrical conductivity and large volumetric changes. Herein, we report a silicon/carbon nanotube (Si/CNT) composite made of an externally grown flexible carbon nanotube (CNT) network to confine inner multiple Silicon (Si) nanoparticles (Si NPs). The in situ generated outer CNTs networks, not only accommodate the large volume changes of inside Si NPs but also to provide fast electronic/ionic diffusion pathways, resulting in a significantly improved cycling stability and rate performance. This Si/CNT composite demonstrated outstanding cycling performance, with 912.8 mAh g(-1) maintained after 100 cycles at 100 mA g(-1), and excellent rate ability of 650 mAh g(-1) at 1 A g(-1) after 1000 cycles. Furthermore, the facial and scalable preparation method created in this work will make this new Si-based anode material promising for practical application in the next generation Li-ion batteries. |
| 资助项目 | National Natural Science Foundation of China[51503109] ; China Postdoctoral Science Foundation[2016M600522] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000633991700001 |
| 出版者 | MDPI |
| 资助机构 | National Natural Science Foundation of China ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/121113]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zhu, Xiaoyi; Zhang, Lei |
| 作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China 2.Qingdao Univ, Chem Expt Teaching Ctr, Sch Mat Sci & Engn, Sch Automat,Sch Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Na,Li, Jianjiang,Wang, Xuechen,et al. Flexible Carbon Nanotubes Confined Yolk-Shelled Silicon-Based Anode with Superior Conductivity for Lithium Storage[J]. NANOMATERIALS,2021,11. |
| APA | Han, Na.,Li, Jianjiang.,Wang, Xuechen.,Zhang, Chuanlong.,Liu, Gang.,...&Zhang, Lei.(2021).Flexible Carbon Nanotubes Confined Yolk-Shelled Silicon-Based Anode with Superior Conductivity for Lithium Storage.NANOMATERIALS,11. |
| MLA | Han, Na,et al."Flexible Carbon Nanotubes Confined Yolk-Shelled Silicon-Based Anode with Superior Conductivity for Lithium Storage".NANOMATERIALS 11(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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