We experimentally demonstrate the post-compression of radially polarized 25 fs pulses at 800 nm central wavelength in a multiple thin plate arrangement for the first time, to the best of our knowledge. Sub-7 fs pulses with 90 µJ energy were obtained after dispersion compensation, corresponding to a compression factor of more than 3.5. Preservation of radial polarization state was confirmed by polarized intensity distribution measurements. Linear projections of the radially polarized pulses were also fully characterized in the temporal domain. © 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement