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Effects of metal catalysts on CO2 gasification reactivity of biomass char

文献类型:期刊论文

作者Huang, Yanqin1,2; Yin, Xiuli1; Wu, Chuangzhi1; Wang, Congwei1; Xie, Jianjun1; Zhou, Zhaoqiu1; Ma, Longlong1; Li, Haibin1
刊名biotechnology advances
出版日期2009-09-01
卷号27期号:5页码:568-572
关键词Fir chars CO2 gasification Metal catalysts XRD SEM Kinetic parameters
ISSN号0734-9750
通讯作者xlyin@ms.giec.ac.cn ; wucz@ms.giec.ac.cn
中文摘要the effects of five metal catalysts (k, na, ca, mg, and fe) on co2 gasification reactivity of fir char were studied using thermal gravimetric analysis. the degree of carbonization, crystal structure and morphology of char samples was characterized by x-ray diffractometry (xrd) and scanning electron microscopy (sem). the co2 gasification reactivity of fir char was improved through the addition of metal catalysts, in the order k>na>ca>fe>mg. xrd analysis indicated that na and ca improved the formation of crystal structure, and that mg enhanced the degree of carbon structure ordering. sem analysis showed that spotted activation centers were distributed on the surface of char samples impregnated with catalysts. moreover, a loose flake structure was observed on the surface of both k-char and na-char. finally, the kinetic parameters of co2 gasification of char samples were calculated mathematically.
英文摘要the effects of five metal catalysts (k, na, ca, mg, and fe) on co2 gasification reactivity of fir char were studied using thermal gravimetric analysis. the degree of carbonization, crystal structure and morphology of char samples was characterized by x-ray diffractometry (xrd) and scanning electron microscopy (sem). the co2 gasification reactivity of fir char was improved through the addition of metal catalysts, in the order k>na>ca>fe>mg. xrd analysis indicated that na and ca improved the formation of crystal structure and that, mg enhanced the degree of carbon structure ordering. sem analysis showed that spotted activation centers were distributed on the surface of char samples impregnated with catalysts. moreover, a loose flake structure was observed on the surface of both k-char and na-char. finally, the kinetic parameters of co2 gasification of char samples were calculated mathematically. (c) 2009 elsevier inc. all rights reserved.
WOS标题词science & technology ; life sciences & biomedicine
类目[WOS]biotechnology & applied microbiology
研究领域[WOS]biotechnology & applied microbiology
关键词[WOS]coal ; carbon ; gasifier ; gas
收录类别SCI ; ISTP
原文出处http://www.sciencedirect.com/science/journal/07349750
语种英语
WOS记录号WOS:000267741300006
公开日期2010-09-16
源URL[http://ir.giec.ac.cn/handle/344007/3324]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Renewable Energy & Gas Hydrate Key Lab, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Huang, Yanqin,Yin, Xiuli,Wu, Chuangzhi,et al. Effects of metal catalysts on CO2 gasification reactivity of biomass char[J]. biotechnology advances,2009,27(5):568-572.
APA Huang, Yanqin.,Yin, Xiuli.,Wu, Chuangzhi.,Wang, Congwei.,Xie, Jianjun.,...&Li, Haibin.(2009).Effects of metal catalysts on CO2 gasification reactivity of biomass char.biotechnology advances,27(5),568-572.
MLA Huang, Yanqin,et al."Effects of metal catalysts on CO2 gasification reactivity of biomass char".biotechnology advances 27.5(2009):568-572.

入库方式: OAI收割

来源:广州能源研究所

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