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Polymeric Membrane Fluoride-Selective Electrodes Using Lewis Acidic Organo-Antimony(V) Compounds as Ionophores

文献类型：期刊论文

作者Li, Long4; Zhang, Yihao4; Li, Ying4; Duan, Yinghui4; Qian, Yi4; Zhang, Peidong4; Guo, Qingjie3; Ding, Jiawang1,2
刊名ACS SENSORS
出版日期2020-11-25
卷号5期号:11页码:3465-3473
关键词polymeric membrane electrode fluoride organo-antimony ionophore potentiometric
ISSN号2379-3694
DOI10.1021/acssensors.0c01481
通讯作者Li, Long(lilongyln@yeah.net)
英文摘要Four Lewis acidic organo-antimony(V) compounds with strong binding affinity to fluoride were used for the first time as ionophores to fabricate polymeric membrane fluoride-selective electrodes. Improved detection limits and significant anti-Hofmeister selectivity could be achieved by optimizing ionophores, lipophilic additives, and plasticizers. Membrane electrodes fabricated with tetrakis-(pentafluorophenyl)stibonium (ionophore 2) performed best in detection limit, sensitivity, and selectivity. Optimal performance was obtained by fluoride with a slope of -59.5 mV/decade in the linear range of 1 X 10(-5) to 4 X 10(-2) M and a detection limit of 5 x 10(-6) M. Studies on the influence of sample solution pH demonstrate that the best pH for fluoride determination is pH 3.0. All of the electrodes studied respond rapidly (in 1 min) in different concentrations of fluoride solutions. The anion-ionophore complex constants in the membrane phase determined using the segmented sandwich membrane method correlate well with the solution-phase binding data and determined selectivity sequence of the ion-selective electrodes. The possibility of real life application of the optimized electrodes was assessed by determination of fluoride concentrations in tap water.
资助项目Key R&D Project of Shandong Province[2019CSF109001] ; Key R&D Project of Shandong Province[2019CSF109080] ; Shandong Provincial Natural Science Foundation, China[ZR2018BB072] ; Original Innovation Project of Qingdao City[19-6-2-23-cg] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2018-K09] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2018-K43] ; Key Laboratory of Coastal Environmental Processes and Ecological Remediation, YIC-CAS[2018KFJJ02] ; Opening Project of Shandong Ecochemical Engineering Collaborative Innovation Center[XTCXQN02] ; Open Project of Chemistry Department of Qingdao University of Science and Technology[QUSTHX201920]
WOS研究方向Chemistry ; Science & Technology - Other Topics
语种英语
WOS记录号WOS:000595550100017
资助机构Key R&D Project of Shandong Province ; Shandong Provincial Natural Science Foundation, China ; Original Innovation Project of Qingdao City ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering ; Key Laboratory of Coastal Environmental Processes and Ecological Remediation, YIC-CAS ; Opening Project of Shandong Ecochemical Engineering Collaborative Innovation Center ; Open Project of Chemistry Department of Qingdao University of Science and Technology
源URL[http://ir.yic.ac.cn/handle/133337/26160]  
专题烟台海岸带研究所_近岸生态与环境实验室
烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
通讯作者Li, Long
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
3.Ningxia Univ, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China
4.Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China
推荐引用方式
GB/T 7714		 Li, Long,Zhang, Yihao,Li, Ying,et al. Polymeric Membrane Fluoride-Selective Electrodes Using Lewis Acidic Organo-Antimony(V) Compounds as Ionophores[J]. ACS SENSORS,2020,5(11):3465-3473.
APA Li, Long.,Zhang, Yihao.,Li, Ying.,Duan, Yinghui.,Qian, Yi.,...&Ding, Jiawang.(2020).Polymeric Membrane Fluoride-Selective Electrodes Using Lewis Acidic Organo-Antimony(V) Compounds as Ionophores.ACS SENSORS,5(11),3465-3473.
MLA Li, Long,et al."Polymeric Membrane Fluoride-Selective Electrodes Using Lewis Acidic Organo-Antimony(V) Compounds as Ionophores".ACS SENSORS 5.11(2020):3465-3473.

入库方式： OAI收割

来源：烟台海岸带研究所

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