Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound
文献类型：期刊论文
| 作者 | Wang, Chen Guang1,3; Wang, Tie Jun1,2; Ma, Long Long1,2; Gao, Yan1,3; Wu, Chuang Zhi1,2 |
| 刊名 | korean journal of chemical engineering
 |
| 出版日期 | 2008-07-01 |
| 卷号 | 25期号:4页码:738-743 |
| 关键词 | biomass fuel gas monolithic catalyst partial oxidation reforming tar elimination |
| 通讯作者 | wangtj@ms.giec.ac.cn |
| 中文摘要 | with naphthalene as biomass tar model compound, partial oxidation reforming (with addition of o-2) and dry reforming of biomass fuel gas were investigated over nickel-based monoliths at the same conditions. the results showed that both processes had excellent performance in upgrading biomass raw fuel gas. above 99% of naphthalene was converted into synthesis gases (h-2+co). about 2.8 wt% of coke deposition was detected on the catalyst surface for dry reforming process at 750 degrees c during 108 h lifetime test. however, no coke deposition was detected for partial oxidation reforming process, which indicated that addition of o-2 can effectively prohibit the coke formation. o-2 can also increase the ch4 conversion and h-2/co ratio of the producer gas. the average conversion of ch4 in dry and partial oxidation reforming process was 92% and 95%, respectively. the average h-2/co ratio increased from 0.95 to 1.1 with the addition of o-2, which was suitable to be used as synthesis gas for dimethyl ether (dme) synthesis. |
| 英文摘要 | with naphthalene as biomass tar model compound, partial oxidation reforming (with addition of o-2) and dry reforming of biomass fuel gas were investigated over nickel-based monoliths at the same conditions. the results showed that both processes had excellent performance in upgrading biomass raw fuel gas. above 99% of naphthalene was converted into synthesis gases (h-2+co). about 2.8 wt% of coke deposition was detected on the catalyst surface for dry reforming process at 750 degrees c during 108 h lifetime test. however, no coke deposition was detected for partial oxidation reforming process, which indicated that addition of o-2 can effectively prohibit the coke formation. o-2 can also increase the ch4 conversion and h-2/co ratio of the producer gas. the average conversion of ch4 in dry and partial oxidation reforming process was 92% and 95%, respectively. the average h-2/co ratio increased from 0.95 to 1.1 with the addition of o-2, which was suitable to be used as synthesis gas for dimethyl ether (dme) synthesis. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, multidisciplinary ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | fluidized-beds ; natural-gas ; gasification ; methane ; combustion ; performance ; elimination ; ni/al2o3 ; reactor ; syngas |
| 收录类别 | SCI |
| 资助信息 | natural science foundation of china [50506030]; natural science foundation of guangdong province, china [06020449] |
| 语种 | 英语 |
| WOS记录号 | WOS:000258549600019 |
| 公开日期 | 2010-09-23 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/3384]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chen Guang,Wang, Tie Jun,Ma, Long Long,et al. Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound[J]. korean journal of chemical engineering,2008,25(4):738-743. |
| APA | Wang, Chen Guang,Wang, Tie Jun,Ma, Long Long,Gao, Yan,&Wu, Chuang Zhi.(2008).Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound.korean journal of chemical engineering,25(4),738-743. |
| MLA | Wang, Chen Guang,et al."Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound".korean journal of chemical engineering 25.4(2008):738-743. |
入库方式： OAI收割
来源：广州能源研究所
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