中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus

文献类型:期刊论文

作者Li, Ke1,3; Siefkes, Michael J.2; Li, Weiming1
刊名JOURNAL OF CHEMICAL ECOLOGY
出版日期2021-02-24
页码5
关键词Metabolites Deer Oxygenated fatty acids Glycine conjugates Integument
ISSN号0098-0331
DOI10.1007/s10886-021-01255-0
通讯作者Li, Weiming(liweim@msu.edu)
英文摘要Sexually mature male deer are known to rub-urinate, a process where urine is deposited on the tarsal gland. The resulting mixture of compounds from urine and secretions from the tarsal gland are used to signal sex, age, maturation status, and other information at close distance. We examined the difference in metabolites of tarsal gland extracts from male and female whitetail deer, Odocoileus virginianus, harvested during the mating season. Using NMR spectroscopy and high-pressure liquid chromatography linked to high resolution mass spectrometry (HPLC/HR-MS) we identified a homologous series of four male-specific compounds. The compounds are novel glycine conjugates of 10-hydroxy-6,9-oxido fatty acids, which we term cervidins A-D. Cervidins were deemed to possess the absolute configuration 6S,9R,10R through comparison of their spectroscopic data with those of known compounds. In addition, cholesterol 3-sulfate and 3-(3-hydroxyphenyl)-propanoic acid were found to be present in the extracts. Our results clearly demonstrate the diversity of potential semiochemicals contained in the mammalian integument.
WOS研究方向Biochemistry & Molecular Biology ; Environmental Sciences & Ecology
语种英语
WOS记录号WOS:000621260100001
源URL[http://ir.yic.ac.cn/handle/133337/27408]  
专题海岸带生物学与生物资源利用重点实验室
海岸带生物资源高效利用研究与发展中心
通讯作者Li, Weiming
作者单位1.Michigan State Univ, Dept Fisheries & Wildlife, E Lansing, MI 48824 USA
2.Great Lakes Fishery Commiss, Ann Arbor, MI 48105 USA
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai, Peoples R China
推荐引用方式
GB/T 7714
Li, Ke,Siefkes, Michael J.,Li, Weiming. Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus[J]. JOURNAL OF CHEMICAL ECOLOGY,2021:5.
APA Li, Ke,Siefkes, Michael J.,&Li, Weiming.(2021).Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus.JOURNAL OF CHEMICAL ECOLOGY,5.
MLA Li, Ke,et al."Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus".JOURNAL OF CHEMICAL ECOLOGY (2021):5.

入库方式: OAI收割

来源:烟台海岸带研究所

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