[Ln(6)O(8)] Cluster-Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion-Exchange Materials for ReO4- Sequestration
文献类型：期刊论文
| 作者 | Lin, J; Zhu, L; Yue, ZH; Yang, C; Liu, W; Albrecht, TE; Wang, JQ; Wang, S |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2019 |
| 卷号 | 6期号:17页码:- |
| 关键词 | KEGGIN POLYOXOMETALATE COORDINATION BORATE CERIUM(IV) COMPLEXES HYDROXIDE CHEMISTRY EVOLUTION ACTINIDES TELLURITE |
| ISSN号 | 2198-3844 |
| DOI | 10.1002/advs.201900381 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Various types of polyoxometalates (POMs) have been synthesized since the 19th century, but their assortment has been mostly limited to Groups 5 and 6 metals. Herein, a new family of POMs composed of a carbon group element as the addenda atoms with two distinct phases, LnPbOClO(4)-1 (Ln = Sm to Ho, Y) and LnPbOClO(4)-2 (Ln = Er and Tm) is reported. Both structures are built from [Ln(6)O(8)] rare-earth metal hexamers being incorporated in [Pb18O32]/[Pb12O24] polyplumbites, and unbound perchlorates as charge-balancing anions. Impressively, YPbOClO4-1 and ErPbOClO4-2 exhibit exceptional uptake capacities (434.7 and 427.7 mg g(-1)) toward ReO4-, a chemical surrogate for the key radioactive fission product in the nuclear fuel cycle (TcO4-)-Tc-99, which are the highest values among all inorganic anion-exchange materials reported until now. The sorption mechanism is clearly elucidated and visualized by single-crystal-to-single-crystal structural transformation from ErPbOClO4-2 to a perrhenate-containing complex ErPbOReO4, revealing a unique ReO4- uptake selectivity driven by specific interaction within Pb center dot center dot center dot O-ReO3- bonds. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31939]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Florida State Univ, Dept Chem & Biochem, 95 Chieftain Way, Tallahassee, FL 32306 USA 2.Southwest Univ Sci & Technol, Natl Coinnovat Ctr Nucl Waste Disposal & Environm, Mianyang 621010, Sichuan, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China; 4.Southwest Univ Sci & Technol, Sch Natl Def Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China; 5.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China; 6.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Suzhou 215123, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Lin, J,Zhu, L,Yue, ZH,et al. [Ln(6)O(8)] Cluster-Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion-Exchange Materials for ReO4- Sequestration[J]. ADVANCED SCIENCE,2019,6(17):-. |
| APA | Lin, J.,Zhu, L.,Yue, ZH.,Yang, C.,Liu, W.,...&Wang, S.(2019).[Ln(6)O(8)] Cluster-Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion-Exchange Materials for ReO4- Sequestration.ADVANCED SCIENCE,6(17),-. |
| MLA | Lin, J,et al."[Ln(6)O(8)] Cluster-Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion-Exchange Materials for ReO4- Sequestration".ADVANCED SCIENCE 6.17(2019):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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