Activating Inert, Nonprecious Perovskites with Iridium Dopants for Efficient Oxygen Evolution Reaction under Acidic Conditions
文献类型：期刊论文
| 作者 | Liang, X; Shi, L; Liu, YP; Chen, H; Si, R; Yan, WS; Zhang, Q; Li, GD; Yang, L; Zou, XX |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019 |
| 卷号 | 58期号:23页码:7631-7635 |
| 关键词 | WATER OXIDATION ELECTROCATALYST CATALYST |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201900796 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Simultaneous realization of improved activity, enhanced stability, and reduced cost remains a desirable yet challenging goal in the search of oxygen evolution electrocatalysts in acid. Herein we report iridium-containing strontium titanates (Ir-STO) as active and stable, low-iridium perovskite electrocatalysts for the oxygen evolution reaction (OER) in acid. The Ir-STO contains 57wt% less iridium relative to the benchmark catalyst IrO2, but it exhibits more than 10times higher catalytic activity for OER. It is shown to be among the most efficient iridium-based oxide electrocatalysts for OER in acid. Theoretical results reveal that the incorporation of iridium dopants in the STO matrix activates the intrinsically inert titanium sites, strengthening the surface oxygen adsorption on titanium sites and thereby giving nonprecious titanium catalytic sites that have activities close to or even better than iridium sites. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31958]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China; 2.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Jilin, Peoples R China; 3.Chinese Acad Sci, Shanghai Synchrotron Radiat Facil, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China; 4.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China; 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, X,Shi, L,Liu, YP,et al. Activating Inert, Nonprecious Perovskites with Iridium Dopants for Efficient Oxygen Evolution Reaction under Acidic Conditions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(23):7631-7635. |
| APA | Liang, X.,Shi, L.,Liu, YP.,Chen, H.,Si, R.,...&Zou, XX.(2019).Activating Inert, Nonprecious Perovskites with Iridium Dopants for Efficient Oxygen Evolution Reaction under Acidic Conditions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(23),7631-7635. |
| MLA | Liang, X,et al."Activating Inert, Nonprecious Perovskites with Iridium Dopants for Efficient Oxygen Evolution Reaction under Acidic Conditions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.23(2019):7631-7635. |
入库方式： OAI收割
来源：上海应用物理研究所
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