An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural
文献类型：期刊论文
| 作者 | Liao, XM; Hou, JD; Wang, Y; Zhang, H; Sun, Y; Li, XP; Tang, SY; Kato, K; Yarnauchi, M; Jiang, Z |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 21期号:15页码:4194-4203 |
| 关键词 | AQUEOUS-PHASE OXIDATION NITROGEN-DOPED CARBON 2,5-FURANDICARBOXYLIC ACID SINGLE-ATOM CO OXIDATION PD/CEO2 CATALYSTS HIGHLY EFFICIENT BASE 2,5-DIFORMYLFURAN NANOPARTICLES |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c9gc01674k |
| 文献子类 | 期刊论文 |
| 英文摘要 | Here we report for the first time a Pd-MnO2 catalyst with a single-atom feature that can convert 5-hydroxylmethyfurfural (HMF) into the important bioplastic building block 2,5-furandicarboxylic acid (FDCA) with a high yield of 88% in aqueous solution using O-2 as an oxidant at ambient pressure. Pd-MnO2 shows higher activity in the productivity of FDCA (100.91 mmol h(-1) g(Pd)(-1)) than its Pd nanoparticle counterpart (45.57 mmol h(-1) g(Pd)(-1)) and state-of-the-art Pd-based catalysts. Pd-MnO2 displays promising recyclability with no degradation after five catalytic runs. Experimental and theoretical results suggest that the single-atom Pd sites that have enhanced binding affinity to HMF and their surrounding sites on the MnO2 support work synergistically toward HMF oxidation. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31961]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Nishi Ku, Motooka 744, Fukuoka, Fukuoka 8190395, Japan; 2.Xihua Univ, Sch Food & Biol Engn, Chengdu 610039, Sichuan, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 5.Hokkaido Univ, Fac Sci, Dept Chem, Kita Ku, N10W8, Sapporo, Hokkaido 0600810, Japan; 6.Chinese Acad Sci, SARI, Key Lab Low Carbon Convers Sci & Engn, 100 Haike Rd, Shanghai 201210, Peoples R China; 7.Sichuan Univ, Sch Chem Engn, Low Carbon Technol & Chem React Engn Lab, Chengdu 610065, Sichuan, Peoples R China; 8.RIKEN, SPring 8 Ctr, 1-1-1 Kouto,Sayo Cho, Mikazuki, Hyogo 6795148, Japan; 9.Chinese Acad Sci, SARI, Shanghai Synchrotron Radiat Facil, Zhangliang Lab, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liao, XM,Hou, JD,Wang, Y,et al. An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural[J]. GREEN CHEMISTRY,2019,21(15):4194-4203. |
| APA | Liao, XM.,Hou, JD.,Wang, Y.,Zhang, H.,Sun, Y.,...&Jiang, Z.(2019).An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural.GREEN CHEMISTRY,21(15),4194-4203. |
| MLA | Liao, XM,et al."An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural".GREEN CHEMISTRY 21.15(2019):4194-4203. |
入库方式： OAI收割
来源：上海应用物理研究所
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