An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoSx Chalcogel for Overall Water Splitting
文献类型：期刊论文
| 作者 | Shan, XY; Liu, J; Mu, HR; Xiao, Y; Mei, BB; Liu, WG; Lin, G; Jiang, Z; Wen, LP; Jiang, L |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019 |
| 卷号 | 59期号:4页码:1659-1665 |
| 关键词 | OXYGEN EVOLUTION REACTION HYDROGEN NANOPARTICLES CATALYSTS DESIGN FILMS CO |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201911617 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The development of high-efficiency electrocatalysts for large-scale water splitting is critical but also challenging. In this study, a hierarchical CoMoSx chalcogel was synthesized on a nickel foam (NF) through an in situ metathesis reaction and demonstrated excellent activity and stability in the electrocatalytic hydrogen evolution reaction and oxygen evolution reaction in alkaline media. The high catalytic activity could be ascribed to the abundant active sites/defects in the amorphous framework and promotion of activity through cobalt doping. Furthermore, the superhydrophilicity and superaerophobicity of micro-/nanostructured CoMoSx/NF promoted mass transfer by facilitating access of electrolytes and ensuring fast release of gas bubbles. By employing CoMoSx/NF as bifunctional electrocatalysts, the overall water splitting device delivered a current density of 500 mA cm(-2) at a low voltage of 1.89 V and maintained its activity without decay for 100 h. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31962]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, CAS Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China; 2.Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266042, Shandong, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shan, XY,Liu, J,Mu, HR,et al. An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoSx Chalcogel for Overall Water Splitting[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,59(4):1659-1665. |
| APA | Shan, XY.,Liu, J.,Mu, HR.,Xiao, Y.,Mei, BB.,...&Jiang, L.(2019).An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoSx Chalcogel for Overall Water Splitting.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(4),1659-1665. |
| MLA | Shan, XY,et al."An Engineered Superhydrophilic/Superaerophobic Electrocatalyst Composed of the Supported CoMoSx Chalcogel for Overall Water Splitting".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.4(2019):1659-1665. |
入库方式： OAI收割
来源：上海应用物理研究所
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