B,N-Doped Defective Carbon Entangled Fe3C Nanoparticles as the Superior Oxygen Reduction Electrocatalyst for Zn-Air Batteries
文献类型：期刊论文
| 作者 | Zhang, GY; Liu, X; Wang, L; Sun, FF; Yang, YQ; Tian, CR; Yu, P; Pan, QW; Fu, HG |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2019 |
| 卷号 | 7期号:23页码:19104-19112 |
| 关键词 | DOPED POROUS CARBON BIFUNCTIONAL ELECTROCATALYST EFFICIENT CATALYST BIOMASS NANOFIBERS NANOSHEETS ALKALINE GRAPHENE ROBUST |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.9b05033 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Improving the oxygen reduction reaction (ORR) activity of the Fe3C-based catalyst is greatly significant for energy conversion devices, such as fuel cells and Zn-air batteries (ZABs). Herein, biomass peanut shell is used to synthesize B,N-codoped defective graphitic carbon entangled Fe3C nano particles (D-BNGFe) via carbonizing and doping, followed by a defect creation process. In the synthesis, the usage of iron species could effectively prevent the formation of the B-N covalent bond, which maximizes the ORR activity. Moreover, a simple acid dissolution process was used to only reserve Fe3C nanoparticles encapsulated by carbon nanostructures, which can be stable during the electrocatalytic ORR as certified by operando X-ray absorption fine structure spectra and transmission electron microscopy characterization. Combining the ORR catalyst of D-BNGFe with the oxygen evolution reaction catalyst of NiFe-LDH@CF (NiFe-LDH grown on the copper foam substrate) as the air cathode, the assembled rechargeable ZABs feature a low-voltage gap, high power density, and excellent stability, which are superior to the state-of-the-art Pt/C + RuO2 and most of the nonprecious metal-based catalysts. This work provides an effective strategy to synthesize Pt-free catalysts derived from the natural plentiful biomass for satisfying the wide application of ZABs. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31972]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ Peoples Republ China, Harbin 150080, Heilongjiang, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, GY,Liu, X,Wang, L,et al. B,N-Doped Defective Carbon Entangled Fe3C Nanoparticles as the Superior Oxygen Reduction Electrocatalyst for Zn-Air Batteries[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(23):19104-19112. |
| APA | Zhang, GY.,Liu, X.,Wang, L.,Sun, FF.,Yang, YQ.,...&Fu, HG.(2019).B,N-Doped Defective Carbon Entangled Fe3C Nanoparticles as the Superior Oxygen Reduction Electrocatalyst for Zn-Air Batteries.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(23),19104-19112. |
| MLA | Zhang, GY,et al."B,N-Doped Defective Carbon Entangled Fe3C Nanoparticles as the Superior Oxygen Reduction Electrocatalyst for Zn-Air Batteries".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.23(2019):19104-19112. |
入库方式： OAI收割
来源：上海应用物理研究所
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