Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution
文献类型：期刊论文
| 作者 | Qiu, SJ; Shen, YL; Wei, GJ; Yao, S; Xi, W; Shu, M; Si, R; Zhang, M; Zhu, JF; An, CH |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2019 |
| 卷号 | 259页码:- |
| 关键词 | H-2 PRODUCTION PLATINUM NANOPARTICLES COCATALYST CATALYSIS GRAPHENE NANOSTRUCTURES HYDROLYSIS GENERATION NANOTUBES COMPOSITE |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2019.118036 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Maximizing the usage of cocatalyst to provide fruitful proton reduction sites and suppress charge carrier recombination is an effective stratagy to dramatically improve the photocatalytic performance. Herein, anchoring single atoms (SAs) of Pt onto the ultrathin porous CdS@carbon dots (CDs) nanosheets has been achieved through in-situ reduction of Pt precursor. X-ray absorption fine structure spectra identify that the single Pt atoms are bonded as Pt-S with a coordination number 4, due to the scattering between platinum center and the sulfur atoms. The Pt single atoms exhibit strong capacity to trap photo-generated electrons, rendering CdS@CDs/Pt-SAs as a class of efficient solar-driven photocatalyst. It shows an outstanding activity towards H-2 generation at rate of 45.5 mmol h(-1) g(-1), which is 133 times of that for bare CdS@CDs. The novel method can be extended to the preparation of various functional nanocatalysts owing to its versatility and facileness. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31987]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China 2.Tianjin Univ Technol, Inst New Energy Mat & Low Carbon Technol, Tianjin Key Lab Organ Solar Cells & Photochem Con, Sch Chem & Chem Engn, Tianjin 300384, Peoples R China; 3.Tianjin Univ Technol, Inst New Energy Mat & Low Carbon Technol, Tianjin Key Lab Adv Funct Porous Mat, Tianjin 300384, Peoples R China; 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Qiu, SJ,Shen, YL,Wei, GJ,et al. Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2019,259:-. |
| APA | Qiu, SJ.,Shen, YL.,Wei, GJ.,Yao, S.,Xi, W.,...&An, CH.(2019).Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution.APPLIED CATALYSIS B-ENVIRONMENTAL,259,-. |
| MLA | Qiu, SJ,et al."Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution".APPLIED CATALYSIS B-ENVIRONMENTAL 259(2019):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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