Dual-Ionically Bound Single-Site Rhodium on Porous Ionic Polymer Rivals Commercial Methanol Carbonylation Catalysts
文献类型：期刊论文
| 作者 | Ren, Z; Lyu, Y; Song, XE; Liu, Y; Jiang, Z; Lin, RH; Ding, YJ |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2019 |
| 页码 | - |
| 关键词 | FIXED-BED HYDROFORMYLATION METAL-ORGANIC FRAMEWORKS HETEROGENOUS CATALYSTS ACID OXIDATION LIQUIDS CONVERSION REACTIVITY PLATFORMS LIGANDS |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201904976 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Novel porous polymers can serve as self-supporting solid carriers and provide abundant coordination or charged sites for single-site metals, and thus are emerging as advanced functional materials in heterogeneous catalysis for various transformations traditionally catalyzed by homogeneous systems. A brief overview of the development of this heterogenization given, including the recent advances regarding electrovalent bonds by employing charged supports represented by porous ionic polymers (PIPs), which is exemplified herein with a novel single-site Rh-1/PIP catalyst, featuring a new active site [Rh(CO)I-3](2-) dual-ionically bound onto a quaternary phosphonium cationic framework polymer, different from the single-ionically bound [Rh(CO)(2)I-2](-) in previous studies. Such a unique metal configuration of Rh-1/PIP leads to excellent performance in vapor-phase methanol carbonylation, outperforming commercial homo- and heterogeneous catalysts. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32030]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China; 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Z,Lyu, Y,Song, XE,et al. Dual-Ionically Bound Single-Site Rhodium on Porous Ionic Polymer Rivals Commercial Methanol Carbonylation Catalysts[J]. ADVANCED MATERIALS,2019:-. |
| APA | Ren, Z.,Lyu, Y.,Song, XE.,Liu, Y.,Jiang, Z.,...&Ding, YJ.(2019).Dual-Ionically Bound Single-Site Rhodium on Porous Ionic Polymer Rivals Commercial Methanol Carbonylation Catalysts.ADVANCED MATERIALS,-. |
| MLA | Ren, Z,et al."Dual-Ionically Bound Single-Site Rhodium on Porous Ionic Polymer Rivals Commercial Methanol Carbonylation Catalysts".ADVANCED MATERIALS (2019):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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