Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts
文献类型：期刊论文
| 作者 | Huang, XY; Wang, P; Zhang, ZC; Zhang, SN; Du, XL; Bi, QY; Huang, FD |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 43期号:33页码:13217-13224 |
| 关键词 | NI CATALYSTS FORMIC-ACID OXIDE TEMPERATURE REDUCTION HYDROGENATION PERFORMANCE NANOTUBES SURFACE COBALT |
| ISSN号 | 1144-0546 |
| DOI | 10.1039/c9nj03152a |
| 文献子类 | 期刊论文 |
| 英文摘要 | Hydrogenation of CO2 toward methane is a promising alternative for CO2 utilization and the development of highly efficient catalysts is the key factor for CO2 methanation. Herein, thin-layer SiOx matrix anchored nickel species catalysts (Ni/SiOx) with high specific surface area and a unique electronic/geometric structure have been successfully fabricated via a hydrothermal strategy. Ni3Si2O5(OH)(4), with a typical layered structure and uniformly dispersed nickel sites, is an ideal precursor for Ni/SiOx catalysts for enhanced CO2 adsorption and chemical activation. The highly dispersed Ni active sites with suitable metal-support interactions with the SiOx matrix can promote CO2 conversion. Moreover, the pore structure and surface physicochemical properties of the Ni/SiOx samples can be tuned by changing the Ni/Si molar ratio. The optimized Ni/SiOx-2 catalyst shows outstanding catalytic efficiency with CO2 conversion of 64.2% and CH4 selectivity of 91.4% as well as excellent long-term (200 h) thermal stability for CO2 methanation under the conditions of 400 degrees C and the high gas hourly space velocity (GHSV) of 90 000 mL g(cat)(-1) h(-1). These findings can open new avenues towards the development of new-type nanomaterials in catalysis, especially renewable C1 chemistry transformations. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32040]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 200031, Peoples R China; 3.Univ Penn, Dept Mat Sci & Engn, 3231 Walnut St, Philadelphia, PA 19104 USA; 4.Peking Univ, State Key Lab Rare Earth Mat Chemist & Applicat, Beijing 100871, Peoples R China; 5.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China; 6.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 7.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Huang, XY,Wang, P,Zhang, ZC,et al. Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts[J]. NEW JOURNAL OF CHEMISTRY,2019,43(33):13217-13224. |
| APA | Huang, XY.,Wang, P.,Zhang, ZC.,Zhang, SN.,Du, XL.,...&Huang, FD.(2019).Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts.NEW JOURNAL OF CHEMISTRY,43(33),13217-13224. |
| MLA | Huang, XY,et al."Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts".NEW JOURNAL OF CHEMISTRY 43.33(2019):13217-13224. |
入库方式： OAI收割
来源：上海应用物理研究所
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