Single-Atom Cr-N-4 Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media
文献类型：期刊论文
| 作者 | Luo, EG; Zhang, H; Wang, X; Gao, LQ; Gong, LY; Zhao, T; Jin, Z; Ge, JJ; Jiang, Z; Liu, CP |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019 |
| 卷号 | 58期号:36页码:12469-12475 |
| 关键词 | N-DOPED CARBON IRON-BASED CATALYSTS ACTIVE-SITES EFFICIENT OXYGEN METAL-COMPLEXES ELECTROCATALYSTS GRAPHENE IDENTIFICATION POLYANILINE ELECTROLYTE |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201906289 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Single-atom catalysts (SACs) are attracting widespread interest for the catalytic oxygen reduction reaction (ORR), with Fe-N-x SACs exhibiting the most promising activity. However, Fe-based catalysts suffer serious stability issues as a result of oxidative corrosion through the Fenton reaction. Herein, using a metal-organic framework as an anchoring matrix, we for the first time obtained pyrolyzed Cr/N/C SACs for the ORR, where the atomically dispersed Cr is confirmed to have a Cr-N-4 coordination structure. The Cr/N/C catalyst exhibits excellent ORR activity with an optimal half-wave potential of 0.773 V versus RHE. More excitingly, the Fenton reaction is substantially reduced and, thus, the final catalysts show superb stability. The innovative and robust active site for the ORR opens a new possibility to circumvent the stability issue of the non-noble metal ORR catalysts. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32206]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Adv Res Inst, Zhangjiang Lab, Shanghai Synchrotron Radiat Facil, Shanghai 201210, Peoples R China; 2.Chinese Acad Sci, Changchun Inst Appl Chem, Jilin Prov Key Lab Low Carbon Chem Power Sources, Lab Adv Power Sources, Changchun 130022, Jilin, Peoples R China; 3.Univ Sci & Technol China, Sch Appl Chem & Engn, Hefei 230026, Anhui, Peoples R China; 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, EG,Zhang, H,Wang, X,et al. Single-Atom Cr-N-4 Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(36):12469-12475. |
| APA | Luo, EG.,Zhang, H.,Wang, X.,Gao, LQ.,Gong, LY.,...&Xing, W.(2019).Single-Atom Cr-N-4 Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(36),12469-12475. |
| MLA | Luo, EG,et al."Single-Atom Cr-N-4 Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.36(2019):12469-12475. |
入库方式： OAI收割
来源：上海应用物理研究所
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