Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide
文献类型：期刊论文
| 作者 | Li, YJ; Chen, XT; Gong, Y |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2019 |
| 卷号 | 48期号:46页码:17158-17162 |
| ISSN号 | 1477-9226 |
| 关键词 | BASE INDUCED REDUCTIONS S HYDROGEN-BONDS C-H ACTIVATION RARE-EARTH LANTHANIDE COMPLEXES COORDINATION POLYMERS ELECTRONIC-STRUCTURE STABILIZATION DEOXYGENATION REACTIVITY |
| DOI | 10.1039/c9dt04234b |
| 文献子类 | 期刊论文 |
| 英文摘要 | A dinuclear Eu(III) complex Eu-2(OCH2NMe2)(2)[N(SiMe3)(2)](4) (1) was synthesized via the reaction of Me3NO and Eu[N(SiMe3)(2)](3), during which the unprecedented C-H activation of Me3NO occurred along with oxygen-atom transfer. A simple Eu[N(SiMe3)(2)](3)(OPMe3) adduct (2) was obtained when Me3PO was used, which should be due to the higher energy barrier and poorer product stability that prevent the formation of the phosphine substituted analogue of 1. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32232]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Nucl Sci & Technol, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Dept Radiochem, Shanghai 201800, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Li, YJ,Chen, XT,Gong, Y. Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide[J]. DALTON TRANSACTIONS,2019,48(46):17158-17162. |
| APA | Li, YJ,Chen, XT,&Gong, Y.(2019).Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide.DALTON TRANSACTIONS,48(46),17158-17162. |
| MLA | Li, YJ,et al."Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide".DALTON TRANSACTIONS 48.46(2019):17158-17162. |
入库方式： OAI收割
来源：上海应用物理研究所
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