The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters
文献类型：期刊论文
| 作者 | Sun, YN; Wang, ED; Ren, YJ; Xiao, K; Liu, X; Yang, D; Gao, Y; Ding, WP; Zhu, Y |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2019 |
| 卷号 | 29期号:38页码:- |
| 关键词 | BONDING PROPERTIES CO OXIDATION NANOCLUSTERS TEMPERATURE ALKYNES COMPLEXES LIGANDS SN |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.201904242 |
| 文献子类 | 期刊论文 |
| 英文摘要 | It is extremely difficult to distinguish the contributions of different sites on the surface and in the inner sites of a catalyst to the overall catalytic performance, as the observed catalytic results reflect an ensemble average from almost all the active sites. How do the inner sites of a catalyst that seem to be not directly involved in a catalytic process exactly contribute to the catalytic performance? Toward this goal, herein the studies not only provide fundamental insights into how the alteration of Au8n+4(SR)(4n+8) clusters by only the inner structure can dramatically change the intrinsic catalytic properties, where Au8n+4(SR)(4n+8) (n = 3, 4, 5) clusters have the same surface motifs but share a periodic kernel structure, but also further demonstrate that the evolution in catalytic activity can potentially be determined by periodic transformation in the inner kernels. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32244]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China; 3.Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China; 4.Nanjing Univ Posts & Telecommun, Sch Mat Sci & Engn, Nanjing 210023, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, YN,Wang, ED,Ren, YJ,et al. The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters[J]. ADVANCED FUNCTIONAL MATERIALS,2019,29(38):-. |
| APA | Sun, YN.,Wang, ED.,Ren, YJ.,Xiao, K.,Liu, X.,...&Zhu, Y.(2019).The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters.ADVANCED FUNCTIONAL MATERIALS,29(38),-. |
| MLA | Sun, YN,et al."The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters".ADVANCED FUNCTIONAL MATERIALS 29.38(2019):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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