A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater
文献类型:期刊论文
作者 | Wu, Yumin3; Qiu, Hui3; Sun, Jiawen1,2; Wang, Yupin3; Gao, Chuanhui3; Liu, Yuetao3 |
刊名 | JOURNAL OF MATERIALS SCIENCE
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出版日期 | 2020-10-22 |
页码 | 13 |
ISSN号 | 0022-2461 |
DOI | 10.1007/s10853-020-05460-2 |
通讯作者 | Liu, Yuetao(yuetaoliu@qust.edu.cn) |
英文摘要 | A type of silsesquioxane-based flexible polyimide aerogel was synthesized by 3,3 ',4,4 '-benzophenonetetracarboxylic dianhydride (BTDA), 4,4 '-diaminodiphenyl and octa(aminopropylsilsesquioxane) (POSS-NH2) with a facile thermal curing and atmospheric drying process. POSS-NH2 was introduced into the polyimide backbone as a cross-linking agent. The obtained aerogel possessed high hydrophobicity with a water contact angle exceeding 143 degrees. And the aerogels showed good cyclic adsorption capacity for various organic solvents, such as acetone, methanol, ethyl acetate, etc. After 15 adsorption experiments, the original adsorption capacity of the aerogels (more than 3 times their own weight) was still maintained. SEM and BET confirmed that the introduction of POSS-NH2 could form a larger pore structure inside the aerogel, thereby achieving an improvement in adsorption performance. The results indicated this kind of aerogel might be flexibly utilized as adsorbent materials for oil pollutants and harmful organic reagents in the field of wastewater treatment. |
资助项目 | Shandong Provincial Natural Science Foundation[ZR2018MB034] ; National Natural Science Foundation of China[51872150] ; Science and technology support plan for Youth Innovation of colleges and universities in Shandong Province[2020KJC005] |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000582363300004 |
出版者 | SPRINGER |
源URL | [http://ir.qdio.ac.cn/handle/337002/168968] ![]() |
专题 | 中国科学院海洋研究所 |
通讯作者 | Liu, Yuetao |
作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao 266237, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Yumin,Qiu, Hui,Sun, Jiawen,et al. A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater[J]. JOURNAL OF MATERIALS SCIENCE,2020:13. |
APA | Wu, Yumin,Qiu, Hui,Sun, Jiawen,Wang, Yupin,Gao, Chuanhui,&Liu, Yuetao.(2020).A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater.JOURNAL OF MATERIALS SCIENCE,13. |
MLA | Wu, Yumin,et al."A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater".JOURNAL OF MATERIALS SCIENCE (2020):13. |
入库方式: OAI收割
来源:海洋研究所
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