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Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction

文献类型：期刊论文

作者Wang, Nan1,3,4; Ma, Shaobo2; Zuo, Pengjian2; Duan, Jizhou1,3,4; Hou, Baorong1,3,4
刊名ADVANCED SCIENCE
出版日期2021-05-27
页码26
关键词application catalytic mechanism electrochemical catalysts hydrogen peroxide two‐ electron oxygen reduction reaction
DOI10.1002/advs.202100076
通讯作者Ma, Shaobo(shaobomahit@gmail.com) ; Zuo, Pengjian(zuopj@hit.edu.cn) ; Duan, Jizhou(duanjz@qdio.ac.cn)
英文摘要Shifting electrochemical oxygen reduction reaction (ORR) via two-electron pathway becomes increasingly crucial as an alternative/green method for hydrogen peroxide (H2O2) generation. Here, the development of 2e(-) ORR catalysts in recent years is reviewed, in aspects of reaction mechanism exploration, types of high-performance catalysts, factors to influence catalytic performance, and potential applications of 2e(-) ORR. Based on the previous theoretical and experimental studies, the underlying 2e(-) ORR catalytic mechanism is firstly unveiled, in aspect of reaction pathway, thermodynamic free energy diagram, limiting potential, and volcano plots. Then, various types of efficient catalysts for producing H2O2 via 2e(-) ORR pathway are summarized. Additionally, the catalytic active sites and factors to influence catalysts' performance, such as electronic structure, carbon defect, functional groups (O, N, B, S, F etc.), synergistic effect, and others (pH, pore structure, steric hindrance effect, etc.) are discussed. The H2O2 electrogeneration via 2e(-) ORR also has various potential applications in wastewater treatment, disinfection, organics degradation, and energy storage. Finally, potential future directions and prospects in 2e(-) ORR catalysts for electrochemically producing H2O2 are examined. These insights may help develop highly active/selective 2e(-) ORR catalysts and shape the potential application of this electrochemical H2O2 producing method.
资助项目Key Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-DQC025] ; National Natural Science Foundation of China[41827805] ; Shandong Key Laboratory of Corrosion Science ; University of Chinese Academy of Sciences (UCAS)
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
语种英语
WOS记录号WOS:000655406800001
出版者WILEY
源URL[http://ir.qdio.ac.cn/handle/337002/171010]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Ma, Shaobo; Zuo, Pengjian; Duan, Jizhou
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Harbin Inst Technol, Sch Chem & Chem Engn, MITT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China
4.Chinese Acad Sci, Ctr Ocean Megasci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Nan,Ma, Shaobo,Zuo, Pengjian,et al. Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction[J]. ADVANCED SCIENCE,2021:26.
APA Wang, Nan,Ma, Shaobo,Zuo, Pengjian,Duan, Jizhou,&Hou, Baorong.(2021).Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction.ADVANCED SCIENCE,26.
MLA Wang, Nan,et al."Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction".ADVANCED SCIENCE (2021):26.

入库方式： OAI收割

来源：海洋研究所

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