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Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts

文献类型：期刊论文

作者Suo, Hongyi3,4,5; Solan, Gregory A.2,4,5; Ma, Yanping4,5; Sun, Wen-Hua1,3,4,5
刊名COORDINATION CHEMISTRY REVIEWS
出版日期2018-10-01
卷号372页码:101-116
关键词Bimetallic complex Early transition metal Late transition metal Catalyst Compartmental ligand Ethylene polymerization Polyethylene microstructure
ISSN号0010-8545
DOI10.1016/j.ccr.2018.06.006
通讯作者Solan, Gregory A.(gas8@leicester.ac.uk) ; Sun, Wen-Hua(whsun@iccas.ac.cn)
英文摘要Recent progress concerning the application of compartmentalized bimetallic complexes as homogeneous catalysts in ethylene polymerization is reviewed with particular regard to metal-metal combinations based on either early- (Ti, Zr, Hf and V) or late-transition metals (Fe, Co and Ni). The effect of positioning two polymerization-active metal centers in close proximity on catalytic activity, molecular weight, molecular weight distribution and levels of branching are thoroughly documented. Compartmental ligands comprising binding domains consisting of phenoxyimines, ansa-bridged cyclopentadienyl-amides, alpha-diimines and iminopyridines are described as is their capacity to serve as compatible binucleating supports for homobimetallic and also for the less investigated heterobimetallic counterparts. By comparison with their mononuclear analogues, any synergic properties exhibited by these binuclear catalysts represents an underlying theme to be developed where possible throughout this review. (C) 2018 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[U1362204] ; National Natural Science Foundation of China[21374123] ; UCAS Joint PhD Training Program[UCAS[2017]17] ; Chinese Academy of Sciences
WOS研究方向Chemistry
语种英语
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China ; UCAS Joint PhD Training Program ; Chinese Academy of Sciences
源URL[http://ir.licp.cn/handle/362003/27221]  
专题兰州化学物理研究所_固体润滑国家重点实验室
通讯作者Solan, Gregory A.; Sun, Wen-Hua
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Leicester, Dept Chem, Univ Rd, Leicester LE1 7RH, Leics, England
3.Univ Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
5.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Suo, Hongyi,Solan, Gregory A.,Ma, Yanping,et al. Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts[J]. COORDINATION CHEMISTRY REVIEWS,2018,372:101-116.
APA Suo, Hongyi,Solan, Gregory A.,Ma, Yanping,&Sun, Wen-Hua.(2018).Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts.COORDINATION CHEMISTRY REVIEWS,372,101-116.
MLA Suo, Hongyi,et al."Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts".COORDINATION CHEMISTRY REVIEWS 372(2018):101-116.

入库方式： OAI收割

来源：兰州化学物理研究所

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