Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions.
文献类型:期刊论文
作者 | Li, MC; Luo, SZ; Wu, PF; Shena, JN |
刊名 | ELECTROCHIMICA ACTA
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出版日期 | 2005-05-30 |
卷号 | 50期号:16-17页码:3401-3406 |
关键词 | titanium dioxide photocathodic protection effect EIS corrosion anodization |
ISSN号 | 0013-4686 |
DOI | 10.1016/j.electacta.2004.12.031 |
通讯作者 | Li, MC(mouchengli@yahoo.com.cn) |
英文摘要 | Titanium dioxide (TiO2) films were prepared by anodization of titanium foils at different voltages in dilute NaOH solutions and characterized by XRD and scanning electron microscopy (SEM) techniques. The thin TiO2 films are mainly composed of anatase phase in the form of nano-crystallites. The photoelectrochemical behavior and photocathodic protection effect, for these films were also investigated in 3% NaCl solutions by using electrochemical measurement techniques and coupling test. The tremendous decrease of film resistance and open circuit potential of each TiO2 film takes place under ultraviolet (UV) illumination. TiO2 film formed at 120 V can serve as photoanode and supply a protective photocurrent about 8 8 mu A/cm(2) to carbon steel, when it is connected to carbon steel in test solution with an area ratio of 2:1. But TiO2 films can accelerate the corrosion of carbon steel in the dark. In addition, electrochemical impedance spectroscopy (EIS) characteristics and coupling behaviors for TiO2 films were discussed in detail. (c) 2005 Elsevier Ltd. All rights reserved. |
WOS研究方向 | Electrochemistry |
语种 | 英语 |
WOS记录号 | WOS:000229570300026 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.imr.ac.cn/handle/321006/83383] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Li, MC |
作者单位 | 1.Shanghai Univ, Inst Mat, Shanghai 200072, Peoples R China 2.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Li, MC,Luo, SZ,Wu, PF,et al. Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions.[J]. ELECTROCHIMICA ACTA,2005,50(16-17):3401-3406. |
APA | Li, MC,Luo, SZ,Wu, PF,&Shena, JN.(2005).Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions..ELECTROCHIMICA ACTA,50(16-17),3401-3406. |
MLA | Li, MC,et al."Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions.".ELECTROCHIMICA ACTA 50.16-17(2005):3401-3406. |
入库方式: OAI收割
来源:金属研究所
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