Syntheses and characterizations of Co(II) and Ni(II) complexes of dihydrobis(thioxotetrazolyl)borato withCo[S-4] and Ni[S4H2] cores
文献类型：期刊论文
| 作者 | Wang, YL; Cao, R; Bi, WH |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2005-03-31 |
| 卷号 | 24期号:5页码:585-591 |
| 关键词 | dihydrobis(thioxotetrazolyi)borato cobalt(II) complex nickel(II) complex Co[S-4] core Ni[S4H2] core electrochemistry |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2004.12.019 |
| 通讯作者 | Cao, R() |
| 英文摘要 | The sodium salt of' the dihydrobis(1-methyl-5-thiotetrazolyl)borato anion [Btt(Me)](-) has been synthesized by the reaction of NaBH4 with 1-methyl-5-thiotetrazole. Treatment of Na[Btt(Me)] with anhydrous CoCl2 and NiCl2 center dot 6H(2)O, respectively, gives the complexes Co(Btt(Me))(2) (1) and Ni(Btt(Me))(2) (2), which have been characterized by IR, H-1 NMR, ESI-MS, UV-Vis spectroscopy as well as X-ray crystallography. Compound 1 contains a central [CoS4] core and exhibits a slightly distorted trigonal-bipyramidal coordination geometry with a very weak apical Co... H-B interaction, whereas 2 features a central [NiS4H2] core in a distorted octahedral coordination geometry and exhibits relatively strong Ni... H-B interactions. These results indicate that the ligand can act in the bidentate (O-S,S) or tridentate (k(3)-S, S,BH) mode. The electrochemical behavior of 1 and 2 has also been investigated by cyclic voltarnmetry. (c) 2005 Elsevier Ltd. All rights reserved. |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000228381600003 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.imr.ac.cn/handle/321006/83646]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Cao, R |
| 作者单位 | Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Grad Sch Chinese Acad Sci, Fujian 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YL,Cao, R,Bi, WH. Syntheses and characterizations of Co(II) and Ni(II) complexes of dihydrobis(thioxotetrazolyl)borato withCo[S-4] and Ni[S4H2] cores[J]. POLYHEDRON,2005,24(5):585-591. |
| APA | Wang, YL,Cao, R,&Bi, WH.(2005).Syntheses and characterizations of Co(II) and Ni(II) complexes of dihydrobis(thioxotetrazolyl)borato withCo[S-4] and Ni[S4H2] cores.POLYHEDRON,24(5),585-591. |
| MLA | Wang, YL,et al."Syntheses and characterizations of Co(II) and Ni(II) complexes of dihydrobis(thioxotetrazolyl)borato withCo[S-4] and Ni[S4H2] cores".POLYHEDRON 24.5(2005):585-591. |
入库方式： OAI收割
来源：金属研究所
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