Single crystal T0.3MoO3 growth by electrolytic reduction method of a T1(2)CO(3)-MoO3 melts
文献类型：期刊论文
| 作者 | Li, CZ; Xiong, R; Yin, D; Tang, Z; Wang, JF; Li, DH; Yu, ZX; Shi, J |
| 刊名 | JOURNAL OF CRYSTAL GROWTH
 |
| 出版日期 | 2005-11-15 |
| 卷号 | 285期号:1-2页码:81-87 |
| 关键词 | electrolytic reduction single crystal growth thallium blue bronze Tl-0.3MoO3 charge density wave |
| ISSN号 | 0022-0248 |
| DOI | 10.1016/j.jcrysgro.2005.07.051 |
| 通讯作者 | Shi, J(jshi@whu.edu.cn) |
| 英文摘要 | Single crystals of quasi-one-dimensional charge-density-wave conductor blue bronze Tl0.3MoO3 have been grown by electrolytic reduction method using the raw materials Tl2CO3-MoO3 with composition around 1:4.3 mol ration. The electrolytic temperature was about 570 degrees C, and electrolytic current was 25 mA during the electrolytic process. By this method, the Tl0.3MoO3 single crystals obtained have a relatively large average size and high quality. Platelet crystals with typical dimensions of 7 x 2 x 1 mm(3) were obtained. The crystal structure is monoclinic with space group C2/m. The parameters of the unit cell of the single crystal are as follows: a = 18.486(6)angstrom, b = 7.555(2)angstrom, c = 10.032(3)angstrom and beta = 118.38(3)degrees. The C-center symmetry of Tl0.3MoO3 crystal is demonstrated by the selected area electron diffraction (SAED) patterns in the transmission electron microscope (TEM). The full-width at half-maximum (FWHM) of the rocking curve of the (201) Bragg peak of the Tl0.3MoO3 was approximately 0.4 degrees. These are evidences that the single crystal is of high quality. The temperature dependence of the resistivity shows that a metal-semiconductor transition occurs near 181 K. (c) 2005 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Crystallography ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000233152500012 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.imr.ac.cn/handle/321006/84023]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Shi, J |
| 作者单位 | 1.Int Ctr Mat Phys, Shenyang 110015, Peoples R China 2.Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, CZ,Xiong, R,Yin, D,et al. Single crystal T0.3MoO3 growth by electrolytic reduction method of a T1(2)CO(3)-MoO3 melts[J]. JOURNAL OF CRYSTAL GROWTH,2005,285(1-2):81-87. |
| APA | Li, CZ.,Xiong, R.,Yin, D.,Tang, Z.,Wang, JF.,...&Shi, J.(2005).Single crystal T0.3MoO3 growth by electrolytic reduction method of a T1(2)CO(3)-MoO3 melts.JOURNAL OF CRYSTAL GROWTH,285(1-2),81-87. |
| MLA | Li, CZ,et al."Single crystal T0.3MoO3 growth by electrolytic reduction method of a T1(2)CO(3)-MoO3 melts".JOURNAL OF CRYSTAL GROWTH 285.1-2(2005):81-87. |
入库方式： OAI收割
来源：金属研究所
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