The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal
文献类型:期刊论文
作者 | Liu, Hong-Gang; Wu, Xiao-Xuan; Zheng, Wen-Chen; He, Lv |
刊名 | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
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出版日期 | 2006-05-01 |
卷号 | 61期号:5-6页码:289-292 |
关键词 | electron paramagnetic resonance crystal- and ligand-field theory defect structure and properties Mn2+ [Zn(H2O)(6)](BF4)(2) |
ISSN号 | 0932-0784 |
通讯作者 | Zheng, Wen-Chen(zhengwe1@163.com) |
英文摘要 | The EPR zero-field splitting D (= b(2)(0)) and its pressure and temperature dependence for trigonal Mn2+ centers in low and room temperature phases in [Zn(H2O)(6)](BF4)(2) : Mn2+ crystal are studied by a high-order perturbation formula based on the dominant spin-orbit coupling mechanism. From the studies, the local trigonal distortion angles, the local angular compressibilities and the local angular thermal expansion coefficients for Mn2+ centers in both phases of the [Zn(H2O)(6)](BF4)(2) crystal are estimated. The results are discussed. |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000239423700013 |
出版者 | VERLAG Z NATURFORSCH |
源URL | [http://ir.imr.ac.cn/handle/321006/88077] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Zheng, Wen-Chen |
作者单位 | 1.Civil Aviat Flying Inst China, Dept Phys, Guanghan 618307, Peoples R China 2.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Hong-Gang,Wu, Xiao-Xuan,Zheng, Wen-Chen,et al. The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2006,61(5-6):289-292. |
APA | Liu, Hong-Gang,Wu, Xiao-Xuan,Zheng, Wen-Chen,&He, Lv.(2006).The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,61(5-6),289-292. |
MLA | Liu, Hong-Gang,et al."The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 61.5-6(2006):289-292. |
入库方式: OAI收割
来源:金属研究所
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