Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units
文献类型：期刊论文
| 作者 | Fang, QR; Zhu, GS; Xue, M; Zhang, QL; Sun, JY; Guo, XD; Qiu, SL; Xu, ST; Wang, P; Wang, DJ |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2006-05-03 |
| 卷号 | 12期号:14页码:3754-3758 |
| 关键词 | hydrogen storage metal-organic frameworks microporous materials photoelectronic properties secondary building units |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.200500963 |
| 通讯作者 | Zhu, GS(sqiu@mail.jlu.edu.cn) |
| 英文摘要 | A novel, three-dimensional, noninterpenetrating microporous metal-organic framework (MOF), [Zn7O2(pda)(5)(H2O)(2)]center dot 5DMF center dot 4EtOH center dot 6H(2)O (1) (H(2)PDA=p-phenylenediacrylic acid, DMF=NN-dimethylformamide, EtOH=ethanol), was synthesized by constructing heptanuclear zinc carboxylate secondary building units (SBUs) and by using rigid and linear aromatic carboxylate ligands, PDA. The X-ray crystallographic data reveals that the seven zinc centers of 1 are held together with ten carboxylate groups of the PDA ligands and four water molecules to form a heptametallic SBU, Zn7O4(CO2)(10), with dimensions of 9.8 x 9.8 x 13.8 angstrom(3). Furthermore, the heptametallic SBUs are interconnected by PDA acting as linkers, thereby generating an extended network with a three-dimensional, noninterpenetrating, intersecting large-channel system with spacing of about 17.3 angstrom. As a microporous framework, polymer 1 shows adsorption behavior that is favorable towards H2O and CH3OH, and substantial H, uptake. In terms of the heptanuclear zinc carboxylate SBUs, polymer I exhibits interesting photo-electronic properties, which would facilitate the exploration of new types of semiconducting materials, especially among MOFs containing multinuclear metal carboxylate SBUs. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000237621900008 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.imr.ac.cn/handle/321006/88245]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhu, GS |
| 作者单位 | 1.Jilin Univ, Coll Chem, Changchun 130023, Peoples R China 2.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 3.Chinese Acad Sci, Met Res Inst, State Key Lab RSA, Shenyang 110016, Peoples R China 4.Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA |
| 推荐引用方式 GB/T 7714 | Fang, QR,Zhu, GS,Xue, M,et al. Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units[J]. CHEMISTRY-A EUROPEAN JOURNAL,2006,12(14):3754-3758. |
| APA | Fang, QR.,Zhu, GS.,Xue, M.,Zhang, QL.,Sun, JY.,...&Wei, Y.(2006).Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units.CHEMISTRY-A EUROPEAN JOURNAL,12(14),3754-3758. |
| MLA | Fang, QR,et al."Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units".CHEMISTRY-A EUROPEAN JOURNAL 12.14(2006):3754-3758. |
入库方式： OAI收割
来源：金属研究所
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