Thermal transition of electrochemically synthesized polyaniline
文献类型：期刊论文
| 作者 | Luo, Kun; Shi, Nanlin; Sun, Chao |
| 刊名 | POLYMER DEGRADATION AND STABILITY
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 91期号:11页码:2660-2664 |
| 关键词 | polyaniline electrochemical synthesis thermal transition crosslinking reaction kinetic parameter |
| ISSN号 | 0141-3910 |
| DOI | 10.1016/j.polymdegradstab.2006.04.027 |
| 通讯作者 | Luo, Kun(kun.luo@manchester.ac.uk) |
| 英文摘要 | The thermal stability of polyaniline (PAni) is of great importance in commercial applications. PAni and its emeraldine base form (PAni-EB) were electrochemically synthesized and subjected to thermogravimetric analysis (TGA) in inert atmosphere, which illustrated that the dopant HClO4 could act as the oxidizing agent at elevated temperature and caused serious decomposition of PAni. Combined with differential scanning calorimetry (DSC), in-situ X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) analyses, the crosslinking reaction among PAni-EB molecules at about 250 degrees C was characterized, and the kinetic parameters were calculated by applying different heating rates in the DSC measurement. (c) 2006 Elsevier Ltd. All rights reserved. |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000241474300015 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.imr.ac.cn/handle/321006/88247]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Luo, Kun |
| 作者单位 | 1.Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England 2.Chinese Acad Sci, Met Res Inst, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Kun,Shi, Nanlin,Sun, Chao. Thermal transition of electrochemically synthesized polyaniline[J]. POLYMER DEGRADATION AND STABILITY,2006,91(11):2660-2664. |
| APA | Luo, Kun,Shi, Nanlin,&Sun, Chao.(2006).Thermal transition of electrochemically synthesized polyaniline.POLYMER DEGRADATION AND STABILITY,91(11),2660-2664. |
| MLA | Luo, Kun,et al."Thermal transition of electrochemically synthesized polyaniline".POLYMER DEGRADATION AND STABILITY 91.11(2006):2660-2664. |
入库方式： OAI收割
来源：金属研究所
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