Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6
文献类型：期刊论文
| 作者 | Kang, Xiang-Dong; Wang, Ping; Cheng, Hui-Ming |
| 刊名 | SCRIPTA MATERIALIA
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 56期号:5页码:361-364 |
| 关键词 | hydrogen storage sodium alanate catalysis thermodynamics |
| ISSN号 | 1359-6462 |
| DOI | 10.1016/j.scriptamat.2006.11.004 |
| 通讯作者 | Wang, Ping(pingwang@imr.ac.cn) |
| 英文摘要 | The effect of the dopant anion on thermodynamic tailoring in TiF3- and TiCl3-doped Na3AlH6 was investigated by pressure-composition desorption isotherm measurements. It was found that the dissociation pressure of the TiF3-doped hydride was substantially higher than that of the TiCl3-doped sample. This finding agrees well with the theoretically demonstrated thermodynamic modification arising upon F- substitution in the hydride lattice, thus providing direct experimental evidence to support functionality of F- anion. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000244109200010 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.imr.ac.cn/handle/321006/89978]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang, Ping |
| 作者单位 | Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Xiang-Dong,Wang, Ping,Cheng, Hui-Ming. Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6[J]. SCRIPTA MATERIALIA,2007,56(5):361-364. |
| APA | Kang, Xiang-Dong,Wang, Ping,&Cheng, Hui-Ming.(2007).Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6.SCRIPTA MATERIALIA,56(5),361-364. |
| MLA | Kang, Xiang-Dong,et al."Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6".SCRIPTA MATERIALIA 56.5(2007):361-364. |
入库方式： OAI收割
来源：金属研究所
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