Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water
文献类型:期刊论文
作者 | Gao, Xin; Wu, Xinqiang; Zhang, Zhaoen; Guan, Hui; Han, En-hou |
刊名 | JOURNAL OF SUPERCRITICAL FLUIDS
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出版日期 | 2007-08-01 |
卷号 | 42期号:1页码:157-163 |
关键词 | supercritical water oxidation stainless steel characterization oxide film |
ISSN号 | 0896-8446 |
DOI | 10.1016/j.supflu.2006.12.020 |
通讯作者 | Gao, Xin(xgao@imr.ac.cn) |
英文摘要 | The characterization of microstructure and chemical compositions of oxide films formed on surfaces of stainless steels is necessary for understanding of corrosion processes and environmentally assisted cracking. In this study, the morphologies, microstructure and chemical compositions of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water (SCW) were investigated using a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer (EDX), an X-ray photoelectron spectroscopy (XPS) analyzer and an X-ray diffraction (XRD) analyzer. A duplex-layer structure was identified in the oxide films. The loose outer layer was rich in Fe, while the compact inner layer was rich in Cr and Fe. In addition, Ni enrichment was observed at the interface between the metal matrix and oxides. The surface oxides tended to change with an increase in water temperature. The possible growth mechanism of the oxide films on 316L stainless steel in SCW environments is believed to be similar to that in high-temperature water, namely metal dissolution/oxide precipitation mechanism and solid-state growth mechanism. (c) 2007 Elsevier B.V. All rights reserved. |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000247337300016 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.imr.ac.cn/handle/321006/90444] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Gao, Xin |
作者单位 | Chinese Acad Sci, Met Res Inst, Environm Corros Ctr, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, Xin,Wu, Xinqiang,Zhang, Zhaoen,et al. Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water[J]. JOURNAL OF SUPERCRITICAL FLUIDS,2007,42(1):157-163. |
APA | Gao, Xin,Wu, Xinqiang,Zhang, Zhaoen,Guan, Hui,&Han, En-hou.(2007).Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water.JOURNAL OF SUPERCRITICAL FLUIDS,42(1),157-163. |
MLA | Gao, Xin,et al."Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water".JOURNAL OF SUPERCRITICAL FLUIDS 42.1(2007):157-163. |
入库方式: OAI收割
来源:金属研究所
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