Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures
文献类型：期刊论文
| 作者 | Li, Hu-Fang1; Kuang, Xiao-Yu1,2; Wang, Huai-Qian1; Mao, Ai-Jie1 |
| 刊名 | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
 |
| 出版日期 | 2008-09-01 |
| 卷号 | 63期号:9页码:609-615 |
| 关键词 | Local Structure Orbital Reduction Effect EPR Spectrum Complete Energy Matrices |
| ISSN号 | 0932-0784 |
| 通讯作者 | Li, Hu-Fang(seu_kxy@163.com) |
| 英文摘要 | The local octahedral environment of Ni2+ in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O crystals with a trigonal distortion has been studied at different temperatures, based on the complete energy matrices. The calculated results showed that the local lattice structure around an octahedral Ni2+ centre in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O exhibits at compression distortion. Simultaneously, the orbital reduction effect on the g factors has been studied. The relationship between Ag =g(parallel to) -g(perpendicular to) and orbital reduction fractor k at 4.2.77 and 298 (302) K has been discussed. suggesting, that there is an almost linear relation between k and Delta g in Ni2+ ion in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O at each temperature. |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000259901400013 |
| 出版者 | VERLAG Z NATURFORSCH |
| 源URL | [http://ir.imr.ac.cn/handle/321006/94211]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Hu-Fang |
| 作者单位 | 1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hu-Fang,Kuang, Xiao-Yu,Wang, Huai-Qian,et al. Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2008,63(9):609-615. |
| APA | Li, Hu-Fang,Kuang, Xiao-Yu,Wang, Huai-Qian,&Mao, Ai-Jie.(2008).Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,63(9),609-615. |
| MLA | Li, Hu-Fang,et al."Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 63.9(2008):609-615. |
入库方式： OAI收割
来源：金属研究所
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