Electrochemical Activity of IrO2 Electrodes in Aqueous Solutions Containing 4-Chlorophenol
文献类型：期刊论文
| 作者 | Wang Xiao-Mei1; Hu Ji-Ming1; Zhang Jian-Qing1,2; Cao Chu-Nan1,2 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 25期号:9页码:1725-1730 |
| 关键词 | Electrochemical activity IrO2 electrode 4-Chlorophenol Aqueous solution Activation |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20090803 |
| 通讯作者 | Hu Ji-Ming(kejmhu@zju.edu.cn) |
| 英文摘要 | The effect of 4-chlorophenol (4-CP) on the electrochemical activity of Ti-based IrO2 electrodes in acidic aqueous solutions was investigated within the electrochemical window for 4-CP. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements both indicated that the existence of 4-CP in solution resulted in the activation of the IrO2 electrode in the electrochemical window. However, the testing results at metallic It electrode showed that the electrode activity was inhibited by 4-CP because of its adsorption onto the metal surface. A possible mechanism is proposed based on the influence of 4-CP on the electrochemical activities of these two electrode materials. The activation of IrO2 is believed to be related to its ease of transition from lower-valent to higher-valent oxides in the electrochemical window. The later oxides can be chemically oxidized and can remove organic molecules that are adsorbed onto the oxide electrode surface. |
| 资助项目 | National Natural Science Foundation of China[20473072] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000269961300003 |
| 出版者 | PEKING UNIV PRESS |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/95910]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Hu Ji-Ming |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, State Key Lab Corros & Protect, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Xiao-Mei,Hu Ji-Ming,Zhang Jian-Qing,et al. Electrochemical Activity of IrO2 Electrodes in Aqueous Solutions Containing 4-Chlorophenol[J]. ACTA PHYSICO-CHIMICA SINICA,2009,25(9):1725-1730. |
| APA | Wang Xiao-Mei,Hu Ji-Ming,Zhang Jian-Qing,&Cao Chu-Nan.(2009).Electrochemical Activity of IrO2 Electrodes in Aqueous Solutions Containing 4-Chlorophenol.ACTA PHYSICO-CHIMICA SINICA,25(9),1725-1730. |
| MLA | Wang Xiao-Mei,et al."Electrochemical Activity of IrO2 Electrodes in Aqueous Solutions Containing 4-Chlorophenol".ACTA PHYSICO-CHIMICA SINICA 25.9(2009):1725-1730. |
入库方式： OAI收割
来源：金属研究所
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