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Study on impedance spectra of La0.7Sr0.3MnO3 and Sm0.2Ce0.8O1.9-impregnated La0.7Sr0.3MnO3 cathode in single chamber fuel cell condition

文献类型:期刊论文

作者Liu, Mingliang1; Lue, Zhe1; Wei, Bo1; Huang, Xiqiang1; Chen, Kongfa1; Su, Wenhui1,2
刊名ELECTROCHIMICA ACTA
出版日期2009-08-01
卷号54期号:20页码:4726-4730
关键词Impedance spectroscopy Strontium-doped LaMnO3 cathode Single chamber fuel cell condition CH4/O-2 ratio Methane-oxygen mixtures
ISSN号0013-4686
DOI10.1016/j.electacta.2009.03.071
通讯作者Lue, Zhe(lvzhe@hit.edu.cn)
英文摘要Impedance spectroscopy was used to study the electrochemical performance of pure and ion-impregnated La0.7Sr0.3MnO3 (LSM) cathodes on YSZ (Y2O3-stabilized ZrO2) electrolytes in single chamber fuel cell conditions, i.e. a mixture gas with oxygen as oxidant, methane as fuel and nitrogen as dilute gas. Measurements were taken at the furnace temperature range of 550-750 degrees C and the CH4/O-2 ratios from 1 to 2. Polarization resistances (R-p) for pure and impregnated LSM cathodes increased obviously as the CH4/O-2 ratio increased at 650-750 degrees C. Polarization resistances of Sm0.2Ce0.8O1.9 (SDC) impregnated LSM cathode were much smaller than the ones of pure LSM cathode under the same conditions. Overtemperatures were occurred at both cathodes due to the partial oxidation of methane. (C) 2009 Elsevier Ltd. All rights reserved.
资助项目Ministry of Science and Technology of China[2007AA05Z139]
WOS研究方向Electrochemistry
语种英语
WOS记录号WOS:000266931800020
出版者PERGAMON-ELSEVIER SCIENCE LTD
资助机构Ministry of Science and Technology of China
源URL[http://ir.imr.ac.cn/handle/321006/95968]  
专题金属研究所_中国科学院金属研究所
通讯作者Lue, Zhe
作者单位1.Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Dept Phys, Harbin 150080, Peoples R China
2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
推荐引用方式
GB/T 7714
Liu, Mingliang,Lue, Zhe,Wei, Bo,et al. Study on impedance spectra of La0.7Sr0.3MnO3 and Sm0.2Ce0.8O1.9-impregnated La0.7Sr0.3MnO3 cathode in single chamber fuel cell condition[J]. ELECTROCHIMICA ACTA,2009,54(20):4726-4730.
APA Liu, Mingliang,Lue, Zhe,Wei, Bo,Huang, Xiqiang,Chen, Kongfa,&Su, Wenhui.(2009).Study on impedance spectra of La0.7Sr0.3MnO3 and Sm0.2Ce0.8O1.9-impregnated La0.7Sr0.3MnO3 cathode in single chamber fuel cell condition.ELECTROCHIMICA ACTA,54(20),4726-4730.
MLA Liu, Mingliang,et al."Study on impedance spectra of La0.7Sr0.3MnO3 and Sm0.2Ce0.8O1.9-impregnated La0.7Sr0.3MnO3 cathode in single chamber fuel cell condition".ELECTROCHIMICA ACTA 54.20(2009):4726-4730.

入库方式: OAI收割

来源:金属研究所

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