THEORETICAL STUDIES OF THE SPIN HAMILTONIAN PARAMETERS AND LOCAL STRUCTURE FOR THE TETRAGONAL Rh2+ CENTER IN RHOMBOHEDRAL BaTiO3
文献类型：期刊论文
| 作者 | Zhang, Hua-Ming1; Wu, Shao-Yi1,2; Wang, Xue-Feng1; Hu, Yue-Xia1 |
| 刊名 | MODERN PHYSICS LETTERS B
 |
| 出版日期 | 2009-07-10 |
| 卷号 | 23期号:17页码:2115-2122 |
| 关键词 | Electron paramagnetic resonance crystal and ligand fields Rh2+ BaTiO3 |
| ISSN号 | 0217-9849 |
| DOI | 10.1142/S0217984909020266 |
| 通讯作者 | Zhang, Hua-Ming() |
| 英文摘要 | The spin Hamiltonian parameters and local structure for the tetragonal Rh2+ center in rhombohedral BaTiO3 are theoretically studied from the perturbation formulas of these parameters for a 4d(7) ion with low spin (S = 1/2) in tetragonally elongated octahedra. This center is ascribed to substitutional Rh2+ at the Ti4+ site in BaTiO3. The [RhO6](10-) cluster suffers relative elongation (characterized by the elongation parameter rho approximate to 0.9%) along the [100] axis due to the Jahn-Teller effect. The tetragonal elongation can entirely depress the slight trigonal distortion of the original Ti4+ site in rhombohedral BaTiO3. The calculated spin Hamiltonian parameters based on the above Jahn-Teller elongation show good agreement with the experimental results. |
| 资助项目 | UESTC |
| WOS研究方向 | Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000268447500004 |
| 出版者 | WORLD SCIENTIFIC PUBL CO PTE LTD |
| 资助机构 | UESTC |
| 源URL | [http://ir.imr.ac.cn/handle/321006/96132]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhang, Hua-Ming |
| 作者单位 | 1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,et al. THEORETICAL STUDIES OF THE SPIN HAMILTONIAN PARAMETERS AND LOCAL STRUCTURE FOR THE TETRAGONAL Rh2+ CENTER IN RHOMBOHEDRAL BaTiO3[J]. MODERN PHYSICS LETTERS B,2009,23(17):2115-2122. |
| APA | Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,&Hu, Yue-Xia.(2009).THEORETICAL STUDIES OF THE SPIN HAMILTONIAN PARAMETERS AND LOCAL STRUCTURE FOR THE TETRAGONAL Rh2+ CENTER IN RHOMBOHEDRAL BaTiO3.MODERN PHYSICS LETTERS B,23(17),2115-2122. |
| MLA | Zhang, Hua-Ming,et al."THEORETICAL STUDIES OF THE SPIN HAMILTONIAN PARAMETERS AND LOCAL STRUCTURE FOR THE TETRAGONAL Rh2+ CENTER IN RHOMBOHEDRAL BaTiO3".MODERN PHYSICS LETTERS B 23.17(2009):2115-2122. |
入库方式： OAI收割
来源：金属研究所
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