Theoretical studies of the spin-Hamiltonian parameters and their stress dependences for Ru3+ and Ir4+ ions in Y3Ga5O12 crystals
文献类型：期刊论文
| 作者 | Su Ping1; He Lv1,2; Zheng Wen-Chen1,3 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2009-04-17 |
| 卷号 | 474期号:1-2页码:31-33 |
| 关键词 | Inorganic compounds Oxide materials Crystal and ligand fields Point defect Electron paramagnetic resonance |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2008.06.118 |
| 通讯作者 | Zheng Wen-Chen(zhengwc1@163.com) |
| 英文摘要 | The spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants A(parallel to), A(perpendicular to)) and the stress dependence of g(perpendicular to) for 4d(5) ion Ru3+ and 5d(5) ion Ir4+ in Y3Ga5O12 (YGG) crystals are calculated from the perturbation formulas related to the low-spin T-2(2) term subjected to the trigonal symmetry crystal field. The calculated results are in reasonable agreement with the experimental values. Based on the calculations, the signs of hyperfine structure constants are suggested, and the local bonding angles beta (between the metal-ligand bond and C-3 axis) and local angular compressibilities d beta/dP(where P parallel to C-3 axis) are obtained for both systems. It is found that the local angle 6 and local angular compressibility d beta/dP of impurity center are different not only from the corresponding values in the host crystal, but also from impurity to impurity. The results are discussed. (C) 2008 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000266952000013 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.imr.ac.cn/handle/321006/96177]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zheng Wen-Chen |
| 作者单位 | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Zhejiang Normal Univ, Dept Phys, Jinhua 321004, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su Ping,He Lv,Zheng Wen-Chen. Theoretical studies of the spin-Hamiltonian parameters and their stress dependences for Ru3+ and Ir4+ ions in Y3Ga5O12 crystals[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2009,474(1-2):31-33. |
| APA | Su Ping,He Lv,&Zheng Wen-Chen.(2009).Theoretical studies of the spin-Hamiltonian parameters and their stress dependences for Ru3+ and Ir4+ ions in Y3Ga5O12 crystals.JOURNAL OF ALLOYS AND COMPOUNDS,474(1-2),31-33. |
| MLA | Su Ping,et al."Theoretical studies of the spin-Hamiltonian parameters and their stress dependences for Ru3+ and Ir4+ ions in Y3Ga5O12 crystals".JOURNAL OF ALLOYS AND COMPOUNDS 474.1-2(2009):31-33. |
入库方式： OAI收割
来源：金属研究所
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