Study on the absorption spectra and electron paramagnetic resonance g factors of RbNiCl3 single crystal
文献类型:期刊论文
作者 | Feng, W. L.1,2,3; Li, X. M.1; Li, T.2; Pu, L. C.2 |
刊名 | PHYSICA B-CONDENSED MATTER
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出版日期 | 2010-09-15 |
卷号 | 405期号:18页码:3831-3833 |
关键词 | Crystal- and ligand-field theory Optical spectra Electron paramagnetic resonance (EPR) Spin-orbit coupling |
ISSN号 | 0921-4526 |
DOI | 10.1016/j.physb.2010.06.011 |
通讯作者 | Feng, W. L.(wenlinfeng@126.com) |
英文摘要 | According to the double-spin-orbit coupling approach and complete diagonalizing (energy matrix) method, the optical absorption spectra and electron paramagnetic resonance g factors (g(vertical bar vertical bar) and g(perpendicular to)) were calculated. The contributions from both the central transitional metal ion (Ni2+) and the ligand (Cl-) have been taken into account, and the calculated results are in good agreement with experimental results. In the calculation, the relation between optical absorption spectra, paramagnetic g factors and the bond angle theta of Ni2+ center in RbNiCl3 has been established. The bond angle theta (approximate to 53.9 degrees) was determined and is consistent with that of experiments, which shows the result is rational. (C) 2010 Elsevier B.V. All rights reserved. |
资助项目 | foundation of Chongqing University of Technology[2008ZQ12] ; foundation of Chongqing University of Technology[2009ZD09] ; terms of science and technology of the Chongqing Education Committee[KJ090608] |
WOS研究方向 | Physics |
语种 | 英语 |
WOS记录号 | WOS:000281170300005 |
出版者 | ELSEVIER SCIENCE BV |
资助机构 | foundation of Chongqing University of Technology ; terms of science and technology of the Chongqing Education Committee |
源URL | [http://ir.imr.ac.cn/handle/321006/99683] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Feng, W. L. |
作者单位 | 1.Chongqing Univ, Key Lab Optoelect Technol & Syst, Minist Educ, Coll Optoelect Engn, Chongqing 400044, Peoples R China 2.Chongqing Univ Technol, Dept Appl Phys, Chongqing 400054, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Feng, W. L.,Li, X. M.,Li, T.,et al. Study on the absorption spectra and electron paramagnetic resonance g factors of RbNiCl3 single crystal[J]. PHYSICA B-CONDENSED MATTER,2010,405(18):3831-3833. |
APA | Feng, W. L.,Li, X. M.,Li, T.,&Pu, L. C..(2010).Study on the absorption spectra and electron paramagnetic resonance g factors of RbNiCl3 single crystal.PHYSICA B-CONDENSED MATTER,405(18),3831-3833. |
MLA | Feng, W. L.,et al."Study on the absorption spectra and electron paramagnetic resonance g factors of RbNiCl3 single crystal".PHYSICA B-CONDENSED MATTER 405.18(2010):3831-3833. |
入库方式: OAI收割
来源:金属研究所
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