Investigations of the Spin Hamiltonian Parameters for the Cu2+ Sites in PrBa2Cu3O6+x and Pr0.5Er0.5Ba2Cu3O6+x
文献类型：期刊论文
| 作者 | Zhang, H. M.2; Wu, S. Y.1,2; Wang, X. F.2; Hu, Y. X.2 |
| 刊名 | JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 23期号:5页码:829-831 |
| 关键词 | Crystal fields and spin Hamiltonians Electron paramagnetic resonance Cu2+ PrBa2Cu3O6+x Pr0.5Er0.5Ba2Cu3O6+x |
| ISSN号 | 1557-1939 |
| DOI | 10.1007/s10948-009-0613-3 |
| 通讯作者 | Zhang, H. M.(huamingzhang66@gmail.com) |
| 英文摘要 | The spin Hamiltonian parameters (the anisotropic g factors g(parallel to) and g(perpendicular to) and the hyperfine structure constants) for the Cu2+ sites in PrBa2Cu3O6+x and Pr0.5Er0.5Ba2Cu3O6+x are theoretically investigated using the high order perturbation formulas of these parameters for a 3d(9) ion in tetragonally elongated octahedra. In these formulas, the tetragonal field parameters are determined from the superposition model and the local structures of the Cu2+ The theoretical spin Hamiltonian parameters are ill good agreement with the observed values for both systems, and the results show improvements as compared with those based on various adjustable covalency coefficients in the previous work. The larger hyperfine structure constants for PrBa2Cu3O6+x than those for Pr0.5Er0.5Ba2Cu3O6+x can be attributed to the weaker covalency clue to the relatively longer Cu2+-O-2 bonds in the former. |
| WOS研究方向 | Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000278546800054 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.imr.ac.cn/handle/321006/99797]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhang, H. M. |
| 作者单位 | 1.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China 2.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, H. M.,Wu, S. Y.,Wang, X. F.,et al. Investigations of the Spin Hamiltonian Parameters for the Cu2+ Sites in PrBa2Cu3O6+x and Pr0.5Er0.5Ba2Cu3O6+x[J]. JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM,2010,23(5):829-831. |
| APA | Zhang, H. M.,Wu, S. Y.,Wang, X. F.,&Hu, Y. X..(2010).Investigations of the Spin Hamiltonian Parameters for the Cu2+ Sites in PrBa2Cu3O6+x and Pr0.5Er0.5Ba2Cu3O6+x.JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM,23(5),829-831. |
| MLA | Zhang, H. M.,et al."Investigations of the Spin Hamiltonian Parameters for the Cu2+ Sites in PrBa2Cu3O6+x and Pr0.5Er0.5Ba2Cu3O6+x".JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM 23.5(2010):829-831. |
入库方式： OAI收割
来源：金属研究所
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