CATHODIC ELECTROCHEMICAL BEHAVIORS OF MILD STEEL IN SEAWATER
文献类型：期刊论文
| 作者 | Zou Yan1; Zheng Yingying1; Wang Yanhua1; Wang Jia1,2 |
| 刊名 | ACTA METALLURGICA SINICA
 |
| 出版日期 | 2010-01-11 |
| 卷号 | 46期号:1页码:123-128 |
| 关键词 | mild steel corrosion in seawater rust layer electrochemical impedance spectrum (EIS) polarization curve |
| ISSN号 | 0412-1961 |
| DOI | 10.3724/SP.J.1037.2009.00374 |
| 通讯作者 | Wang Jia(jwang@ouc.edu.cn) |
| 英文摘要 | The cathodic electrochemical behavior of A3 mild steel in seawater was studied and the roles of the formed rust layers in cathodic process were analyzed by means of electrochemical tests and XRD. The results showed that the rust formed could be classified into outer layer and inner layer. The inner layer is mainly composed of gamma-FeOOH, alpha-FeOOH, beta-FcOOH and Fe(3)O(4)/gamma-Fe(2)O(3), while the main phases in the outer layer changed with the increase of immersion time. During the initial immersion period of 126 d, the phase is gamma-FeOOH; but after about 364 d immersion, the phases are gamma-FeOOH, alpha-FeOOH and Fe(3)O(4)/gamma-Fe(2)O(3). These rust layers play different roles in the cathodic process. Both the outer and inner rust layers can prevent the dissolved oxygen from diffusing into the steel substrate, while the inner layer could also participate in reduction reaction which accelerated the cathodic reaction. A parameter a was induced to evaluate the participation degree of rust in the reduction reaction. The value of parameter alpha obviously increased during the first 7 d immersion, and almost didn't change after 168 d immersion. Changes of components in outer and inner layers were discussed and the interactions of different components were analyzed. |
| 资助项目 | National Natural Science Foundation of China[50971118] |
| WOS研究方向 | Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000274823200020 |
| 出版者 | SCIENCE PRESS |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/99826]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang Jia |
| 作者单位 | 1.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou Yan,Zheng Yingying,Wang Yanhua,et al. CATHODIC ELECTROCHEMICAL BEHAVIORS OF MILD STEEL IN SEAWATER[J]. ACTA METALLURGICA SINICA,2010,46(1):123-128. |
| APA | Zou Yan,Zheng Yingying,Wang Yanhua,&Wang Jia.(2010).CATHODIC ELECTROCHEMICAL BEHAVIORS OF MILD STEEL IN SEAWATER.ACTA METALLURGICA SINICA,46(1),123-128. |
| MLA | Zou Yan,et al."CATHODIC ELECTROCHEMICAL BEHAVIORS OF MILD STEEL IN SEAWATER".ACTA METALLURGICA SINICA 46.1(2010):123-128. |
入库方式： OAI收割
来源：金属研究所
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