Copper corrosion and anodic electrodissolution mechanisms in naturally aerated stagnant 0.5 M H2SO4
文献类型：期刊论文
| 作者 | Lu, Yonghong1; Wang, Wei1; Xu, Haibo1; Kong, Xiangfeng1; Wang, Jia1,2 |
| 刊名 | CORROSION SCIENCE
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 52期号:3页码:780-787 |
| 关键词 | Copper Electrochemical impedance spectroscopy (EIS) Corrosion Electrodissolution Chemical redox |
| ISSN号 | 0010-938X |
| DOI | 10.1016/j.corsci.2009.10.037 |
| 通讯作者 | Xu, Haibo(xuwangri@163.com) |
| 英文摘要 | Mechanisms of copper corrosion and electrodissolution in naturally aerated, stagnant 0.5 M H2SO4 were investigated by means of electrochemical techniques, compared with deaerated measurements. The role of dissolved oxygen was suggested, and three models were proposed in -0.05 similar to 0.15 V vs. SCE range. Near to corrosion potential, chemical redox between cuprous intermediate and oxygen reduction reaction (ORR) intermediate accelerated copper corrosion, and corrosion rate was controlled by a combined cathodic kinetic-anodic diffusion process. in low and high potential ranges, chemical redox, occurred between cuprous intermediate and oxygen molecule, synergistically accelerated the electrodissolution of copper. (C) 2009 Elsevier Ltd. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China[50971118] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000275309900014 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/99973]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xu, Haibo |
| 作者单位 | 1.Ocean Univ China, Coll Chem & Chem Engn, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Shandong, Peoples R China 2.State Key Lab Corros & Protect Met, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Yonghong,Wang, Wei,Xu, Haibo,et al. Copper corrosion and anodic electrodissolution mechanisms in naturally aerated stagnant 0.5 M H2SO4[J]. CORROSION SCIENCE,2010,52(3):780-787. |
| APA | Lu, Yonghong,Wang, Wei,Xu, Haibo,Kong, Xiangfeng,&Wang, Jia.(2010).Copper corrosion and anodic electrodissolution mechanisms in naturally aerated stagnant 0.5 M H2SO4.CORROSION SCIENCE,52(3),780-787. |
| MLA | Lu, Yonghong,et al."Copper corrosion and anodic electrodissolution mechanisms in naturally aerated stagnant 0.5 M H2SO4".CORROSION SCIENCE 52.3(2010):780-787. |
入库方式： OAI收割
来源：金属研究所
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