Identification of MnCr2O4 nano-octahedron in catalysing pitting corrosion of austenitic stainless steels
文献类型：期刊论文
| 作者 | Zheng, S. J.2; Wang, Y. J.2; Zhang, B.2; Zhu, Y. L.2; Liu, C.2; Hu, P.1; Ma, X. L.2 |
| 刊名 | ACTA MATERIALIA
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 58期号:15页码:5070-5085 |
| 关键词 | Scanning/transmission electron microscopy (STEM) Corrosion Catalysis Electrochemistry Stainless steel |
| ISSN号 | 1359-6454 |
| DOI | 10.1016/j.actamat.2010.05.043 |
| 通讯作者 | Ma, X. L.(xlma@imr.ac.cn) |
| 英文摘要 | Pitting corrosion of stainless steels, one of the classical problems in materials science and electrochemistry, is generally believed to originate from the local dissolution in MnS inclusions, which are more or less ubiquitous in stainless steels. However, the initial location where MnS dissolution preferentially occurs is known to be unpredictable, which makes pitting corrosion a major concern. In this work we show, at an atomic scale, the initial site where MnS starts to dissolve in the presence of salt water. Using in situ ex-environment transmission electron microscopy (TEM), we found a number of nano-sized octahedral MnCr2O4 crystals (with a spinel structure and a space group of Fd (3) over barm) embedded in the MnS medium, generating local MnCr2O4/MnS nano-galvanic cells. The TEM experiments combined with first-principles calculations clarified that the nano-octahedron, enclosed by eight {1 1 1} facets with metal terminations, is "malignant", and this acts as the reactive site and catalyses the dissolution of MnS. This work not only uncovers the origin of MnS dissolution in stainless steels, but also presents an atomic-scale evolution in a material's failure which may occur in a wide range of engineering alloys and biomedical instruments serving in wet environments. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China ; National Basic Research Program of China[2009CB623705] ; Chinese Academy of Sciences ; CAS/SAFEA |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000280570500017 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China ; National Basic Research Program of China ; Chinese Academy of Sciences ; CAS/SAFEA |
| 源URL | [http://ir.imr.ac.cn/handle/321006/100082]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Ma, X. L. |
| 作者单位 | 1.Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, S. J.,Wang, Y. J.,Zhang, B.,et al. Identification of MnCr2O4 nano-octahedron in catalysing pitting corrosion of austenitic stainless steels[J]. ACTA MATERIALIA,2010,58(15):5070-5085. |
| APA | Zheng, S. J..,Wang, Y. J..,Zhang, B..,Zhu, Y. L..,Liu, C..,...&Ma, X. L..(2010).Identification of MnCr2O4 nano-octahedron in catalysing pitting corrosion of austenitic stainless steels.ACTA MATERIALIA,58(15),5070-5085. |
| MLA | Zheng, S. J.,et al."Identification of MnCr2O4 nano-octahedron in catalysing pitting corrosion of austenitic stainless steels".ACTA MATERIALIA 58.15(2010):5070-5085. |
入库方式： OAI收割
来源：金属研究所
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