中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Studies of the optical spectrum band positions and spin-Hamiltonian parameters for Pa4+ ion in ThX4 (X=Cl, Br) crystals

文献类型:期刊论文

作者Zheng Wen-Chen1,3; Liu Hong-Gang1; Yang Wei-Qing1,2; Qu Gui-Qiang1
刊名JOURNAL OF LUMINESCENCE
出版日期2010-11-01
卷号130期号:11页码:2133-2135
关键词Optical spectroscopy Electron paramagnetic resonance Crystal field Pa4+ ThCl4 ThBr4
ISSN号0022-2313
DOI10.1016/j.jlumin.2010.06.006
通讯作者Zheng Wen-Chen(zhengwc1@163.com)
英文摘要The optical spectrum band positions and spin-Hamiltonian (SH) parameters (g factors g(vertical bar) and g(perpendicular to) and hyperfine structure constants A(vertical bar) and A(perpendicular to)) for 5f(1) ion Pa4+ at the tetragonal Th4+ site of ThX4 (X=Cl, Br) crystals are calculated from a complete diagonalization (of energy matrix) method (CDM). In the CDM, the magnetic (or Zeeman) interaction and hyperfine interaction terms are added to the Hamiltonian in the conventional CDM and so the optical and EPR spectra data can be studied in a unified way. The calculated results are in reasonable agreement with experimental values. The possible misprints or small errors in the experimental g factors for Pa4+ in ThX4 crystals are pointed out. The results are discussed. (c) 2010 Elsevier B.V. All rights reserved.
资助项目ICMP ; CAS[ICMP 2009001]
WOS研究方向Optics
语种英语
WOS记录号WOS:000281931800026
出版者ELSEVIER SCIENCE BV
资助机构ICMP ; CAS
源URL[http://ir.imr.ac.cn/handle/321006/100105]  
专题金属研究所_中国科学院金属研究所
通讯作者Zheng Wen-Chen
作者单位1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
2.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China
3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Zheng Wen-Chen,Liu Hong-Gang,Yang Wei-Qing,et al. Studies of the optical spectrum band positions and spin-Hamiltonian parameters for Pa4+ ion in ThX4 (X=Cl, Br) crystals[J]. JOURNAL OF LUMINESCENCE,2010,130(11):2133-2135.
APA Zheng Wen-Chen,Liu Hong-Gang,Yang Wei-Qing,&Qu Gui-Qiang.(2010).Studies of the optical spectrum band positions and spin-Hamiltonian parameters for Pa4+ ion in ThX4 (X=Cl, Br) crystals.JOURNAL OF LUMINESCENCE,130(11),2133-2135.
MLA Zheng Wen-Chen,et al."Studies of the optical spectrum band positions and spin-Hamiltonian parameters for Pa4+ ion in ThX4 (X=Cl, Br) crystals".JOURNAL OF LUMINESCENCE 130.11(2010):2133-2135.

入库方式: OAI收割

来源:金属研究所

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